Synthesis of bis-NHC precursors and study of their coordination capabilities
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Show full item recordcomunitat-uji-handle:10234/158176
comunitat-uji-handle2:10234/71324
comunitat-uji-handle3:10234/98504
comunitat-uji-handle4:
TFG-TFMMetadata
Title
Synthesis of bis-NHC precursors and study of their coordination capabilitiesAuthor (s)
Tutor/Supervisor; University.Department
Poyatos, Macarena; Universitat Jaume I. Departament de Química Inorgànica i Orgànica; Sancho Llopis, Juan Vicente; Universitat Jaume I. Departament de Química Física i AnalíticaDate
2021-06-25Publisher
Universitat Jaume IAbstract
N-Heterocyclic carbenes (from now on NHCs) are neutral compounds containing a
divalent carbon atom with six valence electrons and being part of a nitrogen atom
containing heterocycle. Four electrons are involved in ... [+]
N-Heterocyclic carbenes (from now on NHCs) are neutral compounds containing a
divalent carbon atom with six valence electrons and being part of a nitrogen atom
containing heterocycle. Four electrons are involved in σ-bonds and the other two remain
at the central carbon.
Their incomplete electron octet and their coordinative unsaturation, render free carbenes
unstable. Indeed, they were considered only as highly reactive transient intermediates for
decades.
[...] [-]
Subject
Description
Treball Final de Grau en Química. Codi: QU0943. Curs acadèmic: 2020/2021
Type
info:eu-repo/semantics/bachelorThesisRights
info:eu-repo/semantics/openAccess
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- Grau en Química [265]