Multifunctional Polymers Based on Ionic Liquid and Rose Bengal Fragments for the Conversion of CO2 to Carbonates
Impacto
Scholar |
Otros documentos de la autoría: Valverde, David; Porcar Garcia, Raul; Lozano, Pedro; Garcia-Verdugo, Eduardo; Luis, Santiago V.
Metadatos
Mostrar el registro completo del ítemcomunitat-uji-handle:10234/9
comunitat-uji-handle2:10234/7053
comunitat-uji-handle3:10234/8639
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INVESTIGACIONMetadatos
Título
Multifunctional Polymers Based on Ionic Liquid and Rose Bengal Fragments for the Conversion of CO2 to CarbonatesAutoría
Fecha de publicación
2021-01-19Editor
American Chemical SocietyISSN
2168-0485Cita bibliográfica
Valverde, D.; Porcar, R.; Lozano, P.; García-Verdugo, E.; Luis, Santiago V. Multifunctional Polymers Based on Ionic Liquid and Rose Bengal Fragments for the Conversion of CO2 to Carbonates. ACS Sustainable Chemistry & Engineering. 2021, 9 (5), 2309-2318. DOI: 10.1021/acssuschemeng.0c08388Tipo de documento
info:eu-repo/semantics/articleVersión de la editorial
https://pubs.acs.org/doi/abs/10.1021/acssuschemeng.0c08388Versión
info:eu-repo/semantics/publishedVersionPalabras clave / Materias
Resumen
Supported ionic liquid-like phases (SILLPs) containing Rose Bengal (RB) units are used to develop organocatalytic systems for the cycloaddition of CO2 to epoxides. The activity of the supported RB fragments can be ... [+]
Supported ionic liquid-like phases (SILLPs) containing Rose Bengal (RB) units are used to develop organocatalytic systems for the cycloaddition of CO2 to epoxides. The activity of the supported RB fragments can be fine-tuned by controlling the nature of the SILLPs (i.e., substitution at the imidazolium ring, cross-linking degree of the polymeric matrix, loading, etc.). Such a catalytic system prepared from cheap, simple, and commercially available components provides high activity and stability, with no decay in activity for at least 10 days of continuous use under flow conditions. [-]
Publicado en
ACS Sustainable Chemistry and Engineering, 2021, vol. 9, no 5Entidad financiadora
Universitat Jaume I | Ministerio de Ciencia, Innovación y Universidades
Código del proyecto o subvención
UJI-B2019-40 | RTI2018-098233-B-C22 y C21
Derechos de acceso
info:eu-repo/semantics/openAccess
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