Multifunctional Polymers Based on Ionic Liquid and Rose Bengal Fragments for the Conversion of CO2 to Carbonates
Impacte
Scholar |
Altres documents de l'autoria: Valverde, David; Porcar Garcia, Raul; Lozano, Pedro; Garcia-Verdugo, Eduardo; Luis, Santiago V.
Metadades
Mostra el registre complet de l'elementcomunitat-uji-handle:10234/9
comunitat-uji-handle2:10234/7053
comunitat-uji-handle3:10234/8639
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INVESTIGACIONMetadades
Títol
Multifunctional Polymers Based on Ionic Liquid and Rose Bengal Fragments for the Conversion of CO2 to CarbonatesAutoria
Data de publicació
2021-01-19Editor
American Chemical SocietyISSN
2168-0485Cita bibliogràfica
Valverde, D.; Porcar, R.; Lozano, P.; García-Verdugo, E.; Luis, Santiago V. Multifunctional Polymers Based on Ionic Liquid and Rose Bengal Fragments for the Conversion of CO2 to Carbonates. ACS Sustainable Chemistry & Engineering. 2021, 9 (5), 2309-2318. DOI: 10.1021/acssuschemeng.0c08388Tipus de document
info:eu-repo/semantics/articleVersió de l'editorial
https://pubs.acs.org/doi/abs/10.1021/acssuschemeng.0c08388Versió
info:eu-repo/semantics/publishedVersionParaules clau / Matèries
Resum
Supported ionic liquid-like phases (SILLPs) containing Rose Bengal (RB) units are used to develop organocatalytic systems for the cycloaddition of CO2 to epoxides. The activity of the supported RB fragments can be ... [+]
Supported ionic liquid-like phases (SILLPs) containing Rose Bengal (RB) units are used to develop organocatalytic systems for the cycloaddition of CO2 to epoxides. The activity of the supported RB fragments can be fine-tuned by controlling the nature of the SILLPs (i.e., substitution at the imidazolium ring, cross-linking degree of the polymeric matrix, loading, etc.). Such a catalytic system prepared from cheap, simple, and commercially available components provides high activity and stability, with no decay in activity for at least 10 days of continuous use under flow conditions. [-]
Publicat a
ACS Sustainable Chemistry and Engineering, 2021, vol. 9, no 5Entitat finançadora
Universitat Jaume I | Ministerio de Ciencia, Innovación y Universidades
Codi del projecte o subvenció
UJI-B2019-40 | RTI2018-098233-B-C22 y C21
Drets d'accés
info:eu-repo/semantics/openAccess
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