Synergy between supported ionic liquid-like phases and immobilized palladium N-heterocyclic carbene–phosphine complexes for the Negishi reaction under flow conditions
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Metadades
Mostra el registre complet de l'elementcomunitat-uji-handle:10234/9
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comunitat-uji-handle3:10234/8639
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INVESTIGACIONMetadades
Títol
Synergy between supported ionic liquid-like phases and immobilized palladium N-heterocyclic carbene–phosphine complexes for the Negishi reaction under flow conditionsAutoria
Data de publicació
2020Editor
Beilstein-InstitutISSN
1860-5397Cita bibliogràfica
Peris, E.; Porcar, R.; Macia, M.; Alcázar, J.; García-Verdugo, E.; Luis, S. V. Beilstein J. Org. Chem. 2020, 16, 1924–1935. doi:10.3762/bjoc.16.159Tipus de document
info:eu-repo/semantics/articleVersió de l'editorial
https://www.beilstein-journals.org/bjoc/articles/16/159Versió
info:eu-repo/semantics/publishedVersionParaules clau / Matèries
Resum
The combination of supported ionic liquids and immobilized NHC–Pd–RuPhos led to active and more stable systems for the Negishi reaction under continuous flow conditions than those solely based on NHC–Pd–RuPhos. The ... [+]
The combination of supported ionic liquids and immobilized NHC–Pd–RuPhos led to active and more stable systems for the Negishi reaction under continuous flow conditions than those solely based on NHC–Pd–RuPhos. The fine tuning of the NHC–Pd catalyst and the SILLPs is a key factor for the optimization of the release and catch mechanism leading to a catalytic system easily recoverable and reusable for a large number of catalytic cycles enhancing the long-term catalytic performance. [-]
Publicat a
Beilstein journal of organic chemistry, 2020, vol. 16, no 1Proyecto de investigación
Pla de Promoció de la Investigació de la Universitat Jaume I: UJI-B2019-40; Ministerio de Ciencia, Innovación y Universidades: RTI2018-098233-B-C22; MICINN: FPU13/00685Drets d'accés
info:eu-repo/semantics/openAccess
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