A palladium-hinged organometallic square with a perfect-sized cavity for the encapsulation of three heteroguests
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INVESTIGACIONMetadatos
Título
A palladium-hinged organometallic square with a perfect-sized cavity for the encapsulation of three heteroguestsFecha de publicación
2019-12-25Editor
Royal Society of ChemistryISSN
1359-7345; 1364-548XCita bibliográfica
MARTÍNEZ-AGRAMUNT, Víctor; PERIS, Eduardo. A palladium-hinged organometallic square with a perfect-sized cavity for the encapsulation of three heteroguests. Chemical Communications, 2019, vol. 55, no 99, p. 14972-14975.Tipo de documento
info:eu-repo/semantics/articleVersión de la editorial
https://pubs.rsc.org/en/content/articlelanding/2019/CC/C9CC08595E#!divAbstractVersión
info:eu-repo/semantics/submittedVersionPalabras clave / Materias
Resumen
A nanometer-sized tetrapalladium metallosquare with a pyrene-bisimidazolylidene ligand was found to display a perfect-sized cavity for the encapsulation of three heteroguests, enabling the formation of quintuple ... [+]
A nanometer-sized tetrapalladium metallosquare with a pyrene-bisimidazolylidene ligand was found to display a perfect-sized cavity for the encapsulation of three heteroguests, enabling the formation of quintuple D–A–D–A–D stacks. The encapsulating properties of the metallosquare are clearly determined by the presence of the pyrene panels, which endow the metallosquare with a three-dimensional shape, and also behave as effective antennae for π-stacking interactions. [-]
Descripción
This is a pre-print of an article published in Chemical Communications. The final authenticated version is available online at: https://doi.org/10.1039/C9CC08595E.
Publicado en
Chemical Communications, 2019, vol. 55, no 99Proyecto de investigación
Ministerio de Ciencia y Universidades: PGC2018-093382-B-I00; Universitat Jaume I: UJI-B2017-07Derechos de acceso
© The Royal Society of Chemistry
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info:eu-repo/semantics/openAccess
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