Effects of chain length on the size, stability, and electronic structure of redox-active organic– inorganic hybrid polyoxometalate micelles
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Otros documentos de la autoría: Amin, Sharad; Cameron, Jamie; Watts, Julie; Walsh, Darren; Sans, Victor; Newton, Graham
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https://doi.org/10.1039/c9me00060g |
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Título
Effects of chain length on the size, stability, and electronic structure of redox-active organic– inorganic hybrid polyoxometalate micellesFecha de publicación
2019Editor
Royal Society of ChemistryISSN
2058-9689Cita bibliográfica
AMIN, Sharad, et al. Effects of chain length on the size, stability, and electronic structure of redox-active organic–inorganic hybrid polyoxometalate micelles. Molecular Systems Design & Engineering, 2019, vol. 4, no 5, p. 995-999.Tipo de documento
info:eu-repo/semantics/articleVersión de la editorial
https://pubs.rsc.org/en/content/articlelanding/2019/me/c9me00060g#!divAbstractVersión
info:eu-repo/semantics/publishedVersionResumen
Double-chain redox-active surfactants based on hybrid polyoxometalates show solvent-dependent assembly into nanoscale micellar architectures. These organic–inorganic hybrid amphiphiles, of the general formula K6[P2W ... [+]
Double-chain redox-active surfactants based on hybrid polyoxometalates show solvent-dependent assembly into nanoscale micellar architectures. These organic–inorganic hybrid amphiphiles, of the general formula K6[P2W17O61(POC6H4O(CnH2n+1))2], were prepared with varying aliphatic chain lengths (n = 10, 12, 14, 16, 18 and 20) and display different multi-electron redox behaviours in their molecular and supramolecular forms. Furthermore, modification of the length of the hydrophobic tail is an effective strategy for controlling the stability and electronic properties of the supramolecular nanostructures. [-]
Publicado en
Mol. Syst. Des. Eng., 2019, 4, 995Proyecto de investigación
EP/L015633/1 ; EP/P002382/1 ; RPG2016-442 ; CIDEGENT/2018/036Derechos de acceso
This journal is © The Royal Society of Chemistry 2019
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