Effects of chain length on the size, stability, and electronic structure of redox-active organic– inorganic hybrid polyoxometalate micelles
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https://doi.org/10.1039/c9me00060g |
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Títol
Effects of chain length on the size, stability, and electronic structure of redox-active organic– inorganic hybrid polyoxometalate micellesData de publicació
2019Editor
Royal Society of ChemistryISSN
2058-9689Cita bibliogràfica
AMIN, Sharad, et al. Effects of chain length on the size, stability, and electronic structure of redox-active organic–inorganic hybrid polyoxometalate micelles. Molecular Systems Design & Engineering, 2019, vol. 4, no 5, p. 995-999.Tipus de document
info:eu-repo/semantics/articleVersió de l'editorial
https://pubs.rsc.org/en/content/articlelanding/2019/me/c9me00060g#!divAbstractVersió
info:eu-repo/semantics/publishedVersionResum
Double-chain redox-active surfactants based on hybrid polyoxometalates show solvent-dependent assembly into nanoscale micellar architectures. These organic–inorganic hybrid amphiphiles, of the general formula K6[P2W ... [+]
Double-chain redox-active surfactants based on hybrid polyoxometalates show solvent-dependent assembly into nanoscale micellar architectures. These organic–inorganic hybrid amphiphiles, of the general formula K6[P2W17O61(POC6H4O(CnH2n+1))2], were prepared with varying aliphatic chain lengths (n = 10, 12, 14, 16, 18 and 20) and display different multi-electron redox behaviours in their molecular and supramolecular forms. Furthermore, modification of the length of the hydrophobic tail is an effective strategy for controlling the stability and electronic properties of the supramolecular nanostructures. [-]
Publicat a
Mol. Syst. Des. Eng., 2019, 4, 995Proyecto de investigación
EP/L015633/1 ; EP/P002382/1 ; RPG2016-442 ; CIDEGENT/2018/036Drets d'accés
This journal is © The Royal Society of Chemistry 2019
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http://rightsstatements.org/vocab/InC/1.0/
info:eu-repo/semantics/restrictedAccess
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