Improving Catalyst Activity in Hydrocarbon Functionalization by Remote Pyrene-Graphene Stacking
Visualitza/
Impacte
Scholar |
Altres documents de l'autoria: Ballestin, Pilar; Ventura Espinosa, David; Santiago Martín; Martín Solans, Santiago; Caballero, Ana; Mata Martínez, Jose A; Pérez, Pedro J.
Metadades
Mostra el registre complet de l'elementcomunitat-uji-handle:10234/9
comunitat-uji-handle2:10234/160292
comunitat-uji-handle3:10234/160293
comunitat-uji-handle4:
INVESTIGACIONMetadades
Títol
Improving Catalyst Activity in Hydrocarbon Functionalization by Remote Pyrene-Graphene StackingAutoria
Data de publicació
2019Editor
WileyISSN
0947-6539; 1521-3765Cita bibliogràfica
BALLESTIN, Pilar, et al. Improving Catalyst Activity in Hydrocarbon Functionalization by Remote Pyrene‐Graphene Stacking. Chemistry–A European Journal, 2019Tipus de document
info:eu-repo/semantics/articleVersió de l'editorial
https://onlinelibrary.wiley.com/doi/abs/10.1002/chem.201900964Versió
info:eu-repo/semantics/submittedVersionParaules clau / Matèries
Resum
A copper complex bearing an N-heterocyclic carbene ligand with a pyrene "tail" attached to the backbone has been prepared and supported on reduced graphene oxide (rGO). The free and supported copper materials have ... [+]
A copper complex bearing an N-heterocyclic carbene ligand with a pyrene "tail" attached to the backbone has been prepared and supported on reduced graphene oxide (rGO). The free and supported copper materials have been employed as homogeneous and heterogeneous catalysts in the functionalization of hydrocarbons such as n-hexane, cyclohexane, and benzene through incorporation of the CHCO2 Et unit from ethyl diazoacetate. The graphene-anchored complex displays higher reaction rates and induces higher yields than its soluble counterpart, features that can be rationalized in terms of a decrease in electron density at the metal center due to a remote net electronic flux from the supported copper complex to the graphene surface. [-]
Descripció
This is the pre-peer reviewed version of the following article: Improving Catalyst Activity in Hydrocarbon Functionalization by Remote Pyrene-Graphene Stacking, which has been published in final form at https://doi. ... [+]
This is the pre-peer reviewed version of the following article: Improving Catalyst Activity in Hydrocarbon Functionalization by Remote Pyrene-Graphene Stacking, which has been published in final form at https://doi.org/10.1002/chem.201900964. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. [-]
Publicat a
Chemistry-A European Journal, 2019Proyecto de investigación
Ministerio de Economía, Industria y Competitividad, Gobierno de España: CTQ2017-82893-C2-1-R;Ministerio de Economía, Industria y Competitividad, Gobierno de España: CTQ2015-69153-C2-2-R; Consejería de Economía, Innovación, Ciencia y Empleo, Junta de Andalucía: P12-FQM-1765Drets d'accés
© Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
http://rightsstatements.org/vocab/InC/1.0/
info:eu-repo/semantics/openAccess
http://rightsstatements.org/vocab/InC/1.0/
info:eu-repo/semantics/openAccess
Apareix a les col.leccions
- INAM_Articles [528]