A Size‐Flexible Organometallic Box for the Encapsulation of Fullerenes
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Título
A Size‐Flexible Organometallic Box for the Encapsulation of FullerenesAutoría
Fecha de publicación
2019-04-19Editor
WileyISSN
1433-7851; 1521-3773Cita bibliográfica
MARTÍNEZ‐AGRAMUNT, Victor, et al. A size‐flexible organometallic box for the encapsulation of fullerenes. Angewandte Chemie International Edition, 2019, vol. 58, no 17, p. 5682-5686Tipo de documento
info:eu-repo/semantics/articleVersión de la editorial
https://onlinelibrary.wiley.com/doi/full/10.1002/anie.201901586Versión
info:eu-repo/semantics/acceptedVersionPalabras clave / Materias
Resumen
A palladium‐cornered molecular square with four pyrene‐bis(imidazolylidene) bridging ligands is reported. This metallo‐polygon can encapsulate C60 and C70. The X‐ray diffraction structures of the empty cage as well ... [+]
A palladium‐cornered molecular square with four pyrene‐bis(imidazolylidene) bridging ligands is reported. This metallo‐polygon can encapsulate C60 and C70. The X‐ray diffraction structures of the empty cage as well as the cages complexed with both fullerenes are described. The fullerene encapsulation produces perturbations in the structural parameters of the metallo‐square, showing that it can adjust the shape of its cavity to the size of each fullerene. [-]
Publicado en
Angewandte Chemie International Edition, 2019, vol. 58, no 17Proyecto de investigación
Agencia Estatal de Investigación. Grant Number: IJCI-2015-23407; Universitat Jaume I. Grant Number: UJI-B2017-0Derechos de acceso
Copyright © John Wiley & Sons
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