Mostrar el registro sencillo del ítem
The Complex Coordination Landscape of a Digold(I) U‐Shaped Metalloligand
dc.contributor.author | Ibáñez, Susana | |
dc.contributor.author | Poyatos, Macarena | |
dc.contributor.author | Peris, Eduardo | |
dc.date.accessioned | 2019-04-03T10:30:35Z | |
dc.date.available | 2019-04-03T10:30:35Z | |
dc.date.issued | 2018 | |
dc.identifier.citation | IBÁÑEZ, Susana; POYATOS, Macarena; PERIS, Eduardo. The Complex Coordination Landscape of a Digold (I) U‐Shaped Metalloligand. Angewandte Chemie International Edition, 2018, vol. 57, no 51, p. 16816-16820 | ca_CA |
dc.identifier.issn | 1433-7851 | |
dc.identifier.issn | 1521-3773 | |
dc.identifier.uri | http://hdl.handle.net/10234/182179 | |
dc.description | Dedicated to Bob Crabtree on the occasion of his 70th birthday | ca_CA |
dc.description.abstract | A U‐shaped di‐gold metallotweezer with two pyrene‐imidazolylidene edges and a xanthenyl‐bis‐alkynyl connector was prepared. This metallotweezer acts as metalloligand in the presence of Cu+, Tl+, or Ag+, showing three clearly distinct coordination patterns depending on the cation used. The coordination to Cu+ leads to a complex in which the metalloligand is coordinated in a pincer form. The reaction with Tl+ affords a complex in which the ligand is acting as a ϰ2‐(trans)‐chelate ligand. The reaction with Ag+ leads to a self‐assembled structure, with two silver cations encased inside the cavity of a duplex structure formed by two self‐assembled metallotweezers. | ca_CA |
dc.format.extent | 5 p. | ca_CA |
dc.format.mimetype | application/pdf | ca_CA |
dc.language.iso | eng | ca_CA |
dc.publisher | Wiley | ca_CA |
dc.relation.isPartOf | Angewandte Chemie International Edition, 2018, vol. 57, no 51 | ca_CA |
dc.rights | Copyright © John Wiley & Sons, Inc. | ca_CA |
dc.rights.uri | http://rightsstatements.org/vocab/InC/1.0/ | * |
dc.subject | gold | ca_CA |
dc.subject | metalloligands | ca_CA |
dc.subject | metallotweezers | ca_CA |
dc.subject | N-heterocyclic carbenes | ca_CA |
dc.subject | self-assembly | ca_CA |
dc.title | The Complex Coordination Landscape of a Digold(I) U‐Shaped Metalloligand | ca_CA |
dc.type | info:eu-repo/semantics/article | ca_CA |
dc.identifier.doi | https://doi.org/10.1002/anie.201811711 | |
dc.relation.projectID | Universitat Jaume I. Grant Numbers: UJI-B2017-07, UJI-A2017-02 | ca_CA |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | ca_CA |
dc.relation.publisherVersion | https://onlinelibrary.wiley.com/doi/full/10.1002/anie.201811711 | ca_CA |
dc.date.embargoEndDate | 2019-10-31 | |
dc.type.version | info:eu-repo/semantics/acceptedVersion | ca_CA |
Ficheros en el ítem
Este ítem aparece en la(s) siguiente(s) colección(ones)
-
INAM_Articles [509]