Defect tolerant perovskite solar cells from blade coated non-toxic solvents
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Título
Defect tolerant perovskite solar cells from blade coated non-toxic solventsAutoría
Fecha de publicación
2018-09Editor
Royal Society of ChemistryCita bibliográfica
BI, Zhuoneng, et al. Defect tolerant perovskite solar cells from blade coated non-toxic solvents. Journal of Materials Chemistry A, 2018, 6.39: 19085-19093.Tipo de documento
info:eu-repo/semantics/articleVersión de la editorial
https://pubs.rsc.org/en/content/articlehtml/2018/ta/c8ta06771fVersión
info:eu-repo/semantics/submittedVersionPalabras clave / Materias
Resumen
The process of crystallization of lead halide perovskites by industrially relevant techniques involving non-toxic solvents is not understood completely and needs improvement. To this date, devices with the highest ... [+]
The process of crystallization of lead halide perovskites by industrially relevant techniques involving non-toxic solvents is not understood completely and needs improvement. To this date, devices with the highest efficiency are prepared by deposition of the perovskite layer using non-scalable techniques, toxic solvents and/or require additional processing steps. In this work, we show that perovskite solar cells can be obtained efficiently in one step by doctor blade. The perovskite film is formed under a supersaturation regime from non-toxic solvents following spherulitic growth. This method results in highly crystalline perovskite films with preferential crystal orientation. Co-local photoluminescence and light-beam induced current experiments show that the generated chemical defects are confined at the boundary of spherulites and do not have a negative effect on the extracted photocurrent. Strikingly, spherulite formation, rather than being detrimental, could lead to better photovoltaic performance in hybrid perovskite films. This is further confirmed in the photovoltaic devices, which were fabricated using non-toxic solvents by doctor blade process, with record efficiencies of 18.0% for MAPbI3 (MA = methyl ammonium). Moreover, devices with large area (1.53 cm2) fabricated using doctor blade show remarkable efficiencies (14.2%) reinforcing the viability of this solar technology towards industrialization. [-]
Proyecto de investigación
Spanish Ministerio de Economía y Competitividad (MINECO) (MAT2016-76892-C3-1-R, MAT2015-70850-P (HIBRI2), (Ramón y Cajal Fellowship number RYC-2014-16809), (Spanish Severo Ochoa Centre of Excellence (ICMAB), Grant No. SEV-2015-0496) ; ollaborative Innovation and Environmental Construction Platform of Guangdong Province (2014A050503051) ; University Jaume I (UJI-B2017-32) ; European Research Council (ERC) (grant agreement no. 648901).Derechos de acceso
© The Royal Society of Chemistry 2018
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info:eu-repo/semantics/openAccess
http://rightsstatements.org/vocab/InC/1.0/
info:eu-repo/semantics/openAccess
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