Dimethyl carbonate as a non-innocent benign solvent for the multistep continuous flow synthesis of amino alcohols
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Other documents of the author: Porcar Garcia, Raul; Lozano, Pedro; Burguete, M. Isabel; Garcia-Verdugo, Eduardo; Luis, Santiago V.
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comunitat-uji-handle2:10234/7053
comunitat-uji-handle3:10234/8639
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https://doi.org/10.1039/C8RE00097B |
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Title
Dimethyl carbonate as a non-innocent benign solvent for the multistep continuous flow synthesis of amino alcoholsAuthor (s)
Date
2018Publisher
Royal Society of ChemistryISSN
2058-9883Bibliographic citation
Porcar, Raul, et al. "Dimethyl carbonate as a non-innocent benign solvent for the multistep continuous flow synthesis of amino alcohols." Reaction Chemistry & Engineering 3.4 (2018): 572-578Type
info:eu-repo/semantics/articlePublisher version
https://pubs.rsc.org/en/content/articlelanding/2018/re/c8re00097bVersion
info:eu-repo/semantics/publishedVersionAbstract
An efficient methodology for the production and resolution of amino alcohols with a low environmental impact has been developed. The system is based on the assembly of three different well compartmentalised catalytic ... [+]
An efficient methodology for the production and resolution of amino alcohols with a low environmental impact has been developed. The system is based on the assembly of three different well compartmentalised catalytic modules allowing the combination of catalytic and biocatalytic elements. Dimethyl carbonate is used as a green but non-innocent solvent, playing a dual role as the solvent and reagent for two out of the three synthetic steps considered. The use of polymer-supported ionic liquids (SILLPS) is key for the development of some of the catalytic systems optimised. [-]
Is part of
Reaction Chemistry & Engineering, 2018, núm. 4, p. 572-578Investigation project
Financial support from MINECO (CTQ2015-68429-R and CTQ2015-67927-R), Generalitat Valenciana (PROMETEO/2016/ 071) and Comunidad Autónoma de la Región de Murcia (CARM Seneca 19278/PI/14) is acknowledgedRights
This journal is © The Royal Society of Chemistry 2018
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