Selective hydrosilylation of Alkynes to obtanin vinyl-silanes using a Pt-NHC complex
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Title
Selective hydrosilylation of Alkynes to obtanin vinyl-silanes using a Pt-NHC complexAuthor (s)
Tutor/Supervisor; University.Department
Mata Martínez, José Antonio; Universitat Jaume I. Departament de Química Inorgànica i OrgànicaDate
2018-07Publisher
Universitat Jaume IAbstract
The aim of this work is to study the catalytic properties of a platinum molecular
complex and the related hybrid material prepared by immobilization of the
molecular complex onto reduced graphene oxide by non-covalent ... [+]
The aim of this work is to study the catalytic properties of a platinum molecular
complex and the related hybrid material prepared by immobilization of the
molecular complex onto reduced graphene oxide by non-covalent interactions.
This objective can be divided into the following items:
• Synthesis and characterization of an imidazolium salt that would serve as
ligand precursor.
• Synthesis of a new Pt-NHC complex and full characterization by 1H NMR,
APT NMR, COSY, HMBC, HRMS, X-Ray diffraction and TGA
• Immobilization and characterization by TEM and ICP-MS of the Pt-NHC
complex onto rGO
• Study of the catalyst properties of both systems in the hydrosilylation of
alkynes.
• Study of recyclability of the hybrid material in the hydrosilylation of
alkynes.
• Study the mechanism of the hydrosilylation of alkynes reaction [-]
Subject
Description
Treball Final de Màster Universitari en Química Aplicada i Farmacològica. Codi: SIM138. Curs: 2017/2018
Type
info:eu-repo/semantics/masterThesisRights
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