Catalytic coupling of hidrosilanes with alcohols mediated by ruthenium complexes immobilized onto reduced graphene oxide
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Title
Catalytic coupling of hidrosilanes with alcohols mediated by ruthenium complexes immobilized onto reduced graphene oxideAuthor (s)
Tutor/Supervisor; University.Department
Mata Martínez, José Antonio; Universitat Jaume I. Departament de Química Inorgànica i OrgànicaDate
2017Publisher
Universitat Jaume IAbstract
The aim of this work is to study the catalytic dehydrogenative coupling of
hydrosilanes with alcohols using the ruthenium molecular complex and the
related hybrid material prepared by the immobilization of the ... [+]
The aim of this work is to study the catalytic dehydrogenative coupling of
hydrosilanes with alcohols using the ruthenium molecular complex and the
related hybrid material prepared by the immobilization of the molecular
complex onto reduced graphene oxide by non-covalent interactions. In this
study we have focused our interest on different items:
• Synthesis of well-known imidazolium salt that serve as ligand
precursor.
• Synthesis of ruthenium complex and full characterization by 1H NMR,
13C NMR and Mass Spectrometry.
• Synthesis of hybrid material Ru-rGO and characterization by TEM and
ICP-MS.
• Study of the catalytic activity of ruthenium complex and hybrid
material in the coupling of hydrosilanes with alcohols. [-]
Subject
Description
Treball Final del Màster Universitari en Química Aplicada i Farmacològica. Codi: SIM138. Curs acadèmic 2016/2017
Type
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