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Smart N-Heterocyclic Carbene Ligands in Catalysis
dc.contributor.author | Peris, Eduardo | |
dc.date.accessioned | 2018-03-20T08:28:24Z | |
dc.date.available | 2018-03-20T08:28:24Z | |
dc.date.issued | 2017 | |
dc.identifier.citation | PERIS, Eduardo. Smart N-Heterocyclic carbene ligands in catalysis. Chemical reviews, 2017 | ca_CA |
dc.identifier.issn | 0009-2665 | |
dc.identifier.issn | 1520-6890 | |
dc.identifier.uri | http://hdl.handle.net/10234/173469 | |
dc.description.abstract | It is well-recognized that N-heterocyclic carbene (NHC) ligands have provided a new dimension to the design of homogeneous catalysts. Part of the success of this type of ligands resides in the limitless access to a variety of topologies with tuned electronic properties, but also in the ability of a family of NHCs that are able to adapt their properties to the specific requirements of individual catalytic transformations. The term "smart" is used here to refer to switchable, multifunctional, adaptable, or tunable ligands and, in general, to all those ligands that are able to modify their steric or electronic properties to fulfill the requirements of a defined catalytic reaction. The purpose of this review is to comprehensively describe all types of smart NHC ligands by focusing attention on the catalytically relevant ligand-based reactivity. | ca_CA |
dc.format.extent | 44 p. | ca_CA |
dc.format.mimetype | application/pdf | ca_CA |
dc.language.iso | eng | ca_CA |
dc.publisher | American Chemical Society | ca_CA |
dc.relation.isPartOf | Chemical reviews, 2017 | ca_CA |
dc.rights | Copyright © American Chemical Society | ca_CA |
dc.rights.uri | http://rightsstatements.org/vocab/InC/1.0/ | * |
dc.subject | catalysis | ca_CA |
dc.subject | Nheterocyclic carbene | ca_CA |
dc.title | Smart N-Heterocyclic Carbene Ligands in Catalysis | ca_CA |
dc.type | info:eu-repo/semantics/article | ca_CA |
dc.identifier.doi | http://dx.doi.org/10.1021/acs.chemrev.6b00695 | |
dc.rights.accessRights | info:eu-repo/semantics/restrictedAccess | ca_CA |
dc.relation.publisherVersion | https://pubs.acs.org/doi/full/10.1021/acs.chemrev.6b00695 | ca_CA |
dc.contributor.funder | I thank the QOMCAT group from the Universitat Jaume I for their continuous support. I am very thankful to Professor Dmitry G. Gusev (Wilfrid Laurier University) and to Macarena Poyatos (Universitat Jaume I) for their valuable help and for revising the content of this review article. I gratefully acknowledge financial support from the Ministerio de Economía y Competitividad (MINECO) of Spain (CTQ2014-51999-P) and Universitat Jaume I (P11B2014-02). | ca_CA |
dc.type.version | info:eu-repo/semantics/publishedVersion | ca_CA |
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