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Synthesis, molecular structures and EPR spectra of the paramagnetic cuboidal clusters with Mo3S4Ga cores

dc.contributor.authorPetrov, Pavel A.
dc.contributor.authorNaumov, Dmitry Yu.
dc.contributor.authorSukhikh, Taisiya S.
dc.contributor.authorKonchenko, Sergey N.
dc.contributor.authorGómez García, Carlos J.
dc.contributor.authorLlusar, Rosa
dc.date.accessioned2017-11-28T11:29:09Z
dc.date.available2017-11-28T11:29:09Z
dc.date.issued2017
dc.identifier.citationNew J. Chem., 2017,41, 7849-7852ca_CA
dc.identifier.issn1144-0546
dc.identifier.issn1369-9261
dc.identifier.urihttp://hdl.handle.net/10234/170551
dc.description.abstractElectron precise [Mo3(l3-S)(l-S)3(diphos)3Br3]Br (diphos = dppe, dmpe) incomplete cuboidal clusters with six cluster skeletal electrons (CSE) were converted into paramagnetic cuboidal [Mo3(GaBr)(l3-S)4- (diphos)3Br3] clusters by treatment with elemental Ga. The new heterobimetallic complexes with nine CSE possess a doublet ground state with the unpaired electron density delocalized over the three molybdenum atoms.ca_CA
dc.format.extent4 p.ca_CA
dc.format.mimetypeapplication/pdfca_CA
dc.language.isoengca_CA
dc.publisherRoyal Society of Chemistryca_CA
dc.relation.isPartOfNew J. Chem., 2017, 41ca_CA
dc.rightsThis journal is © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2017. This article is licensed under a Creative Commons Attribution-NonComercial 4.0 Unported License.ca_CA
dc.rightsAtribución-NoComercial 4.0 Internacional*
dc.rights.urihttp://creativecommons.org/licenses/by-nc/4.0/*
dc.titleSynthesis, molecular structures and EPR spectra of the paramagnetic cuboidal clusters with Mo3S4Ga coresca_CA
dc.typeinfo:eu-repo/semantics/articleca_CA
dc.identifier.doihttp://doi.org/10.1039/c7nj01217a
dc.relation.projectIDCTQ2015- 65207-P ; PrometeoII/2014/022ca_CA
dc.rights.accessRightsinfo:eu-repo/semantics/openAccessca_CA
dc.relation.publisherVersionhttp://pubs.rsc.org/en/content/articlelanding/2017/nj/c7nj01217a#!divAbstractca_CA
dc.type.versioninfo:eu-repo/semantics/publishedVersionca_CA


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This journal is © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2017. This article is licensed under a Creative Commons Attribution-NonComercial 4.0 Unported License.
Excepto si se señala otra cosa, la licencia del ítem se describe como: This journal is © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2017. This article is licensed under a Creative Commons Attribution-NonComercial 4.0 Unported License.