A D3h-symmetry hexaazatriphenylene-tris-N-heterocyclic carbene ligand and its coordination to iridium and gold: preliminary catalytic studies
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Title
A D3h-symmetry hexaazatriphenylene-tris-N-heterocyclic carbene ligand and its coordination to iridium and gold: preliminary catalytic studiesDate
2017Publisher
Royal Society of ChemistryISSN
1359-7345; 1364-548XBibliographic citation
IBÁÑEZ, S.; POYATOS, M.; PERIS, E. AD 3h-symmetry hexaazatriphenylene-tris-N-heterocyclic carbene ligand and its coordination to iridium and gold: preliminary catalytic studies. Chemical Communications, 2017, vol. 53, no 26, p. 3733-3736.Type
info:eu-repo/semantics/articleVersion
info:eu-repo/semantics/publishedVersionSubject
Abstract
A new D3h-symmetry tris-N-heterocyclic carbene ligand has been prepared and coordinated to iridium and gold. The ligand contains an electron-poor hexaazatriphenylene core; thus, the resulting tris-NHC ligand is a poor ... [+]
A new D3h-symmetry tris-N-heterocyclic carbene ligand has been prepared and coordinated to iridium and gold. The ligand contains an electron-poor hexaazatriphenylene core; thus, the resulting tris-NHC ligand is a poor electron donor. The tris–Au(I) complex was tested in the hydroamination of terminal alkynes and in the three-component Strecker reaction. [-]
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Chemical Communications, 2017, vol. 53, no 26Rights
info:eu-repo/semantics/openAccess
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