Interplay of host volume variations and internal distortions in the course of intercalation into disordered matrices
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Otros documentos de la autoría: Garcia-Belmonte, Germà; Vakarin, Eduard V.; Badiali, Jean Pierre
Metadatos
Mostrar el registro completo del ítemcomunitat-uji-handle:10234/9
comunitat-uji-handle2:10234/2507
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Título
Interplay of host volume variations and internal distortions in the course of intercalation into disordered matricesFecha de publicación
2007ISSN
00219606Tipo de documento
info:eu-repo/semantics/articleVersión de la editorial
http://aip.scitation.org/doi/10.1063/1.2743410Versión
info:eu-repo/semantics/publishedVersionPalabras clave / Materias
Resumen
Based on a combination of the distortive lattice gas model and the maximum information entropy approach, the thermodynamics of insertion into disordered hosts is analyzed. It is found that the isotherm specificities ... [+]
Based on a combination of the distortive lattice gas model and the maximum information entropy approach, the thermodynamics of insertion into disordered hosts is analyzed. It is found that the isotherm specificities can be explained as a cooperative interplay of the host volume expansion and the internal distortions, which tend to optimize the host structure inducing a local lowering of the insertion energetic cost. Behavior of amorphous Lix W O3 films of different thicknesses is discussed in this context. [-]
Publicado en
Journal of Chemical Physics, 126Derechos de acceso
© 2007 American Institute of Physics
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