Interplay of host volume variations and internal distortions in the course of intercalation into disordered matrices
Impact
Scholar |
Other documents of the author: Garcia-Belmonte, Germà; Vakarin, Eduard V.; Badiali, Jean Pierre
Metadata
Show full item recordcomunitat-uji-handle:10234/9
comunitat-uji-handle2:10234/2507
comunitat-uji-handle3:10234/6973
comunitat-uji-handle4:
INVESTIGACIONMetadata
Title
Interplay of host volume variations and internal distortions in the course of intercalation into disordered matricesDate
2007ISSN
00219606Type
info:eu-repo/semantics/articlePublisher version
http://aip.scitation.org/doi/10.1063/1.2743410Version
info:eu-repo/semantics/publishedVersionSubject
Abstract
Based on a combination of the distortive lattice gas model and the maximum information entropy approach, the thermodynamics of insertion into disordered hosts is analyzed. It is found that the isotherm specificities ... [+]
Based on a combination of the distortive lattice gas model and the maximum information entropy approach, the thermodynamics of insertion into disordered hosts is analyzed. It is found that the isotherm specificities can be explained as a cooperative interplay of the host volume expansion and the internal distortions, which tend to optimize the host structure inducing a local lowering of the insertion energetic cost. Behavior of amorphous Lix W O3 films of different thicknesses is discussed in this context. [-]
Is part of
Journal of Chemical Physics, 126Rights
© 2007 American Institute of Physics
http://rightsstatements.org/vocab/InC/1.0/
info:eu-repo/semantics/openAccess
http://rightsstatements.org/vocab/InC/1.0/
info:eu-repo/semantics/openAccess
This item appears in the folowing collection(s)
- FCA_Articles [501]