Interplay of host volume variations and internal distortions in the course of intercalation into disordered matrices
Impacte
Scholar |
Altres documents de l'autoria: Garcia-Belmonte, Germà; Vakarin, Eduard V.; Badiali, Jean Pierre
Metadades
Mostra el registre complet de l'elementcomunitat-uji-handle:10234/9
comunitat-uji-handle2:10234/2507
comunitat-uji-handle3:10234/6973
comunitat-uji-handle4:
INVESTIGACIONMetadades
Títol
Interplay of host volume variations and internal distortions in the course of intercalation into disordered matricesData de publicació
2007ISSN
00219606Tipus de document
info:eu-repo/semantics/articleVersió de l'editorial
http://aip.scitation.org/doi/10.1063/1.2743410Versió
info:eu-repo/semantics/publishedVersionParaules clau / Matèries
Resum
Based on a combination of the distortive lattice gas model and the maximum information entropy approach, the thermodynamics of insertion into disordered hosts is analyzed. It is found that the isotherm specificities ... [+]
Based on a combination of the distortive lattice gas model and the maximum information entropy approach, the thermodynamics of insertion into disordered hosts is analyzed. It is found that the isotherm specificities can be explained as a cooperative interplay of the host volume expansion and the internal distortions, which tend to optimize the host structure inducing a local lowering of the insertion energetic cost. Behavior of amorphous Lix W O3 films of different thicknesses is discussed in this context. [-]
Publicat a
Journal of Chemical Physics, 126Drets d'accés
© 2007 American Institute of Physics
http://rightsstatements.org/vocab/InC/1.0/
info:eu-repo/semantics/openAccess
http://rightsstatements.org/vocab/InC/1.0/
info:eu-repo/semantics/openAccess
Apareix a les col.leccions
- FCA_Articles [501]