Rational design of a supramolecular gel based on a Zn(II)–salophen bis-dipeptide derivative
Impact
![Google Scholar](/xmlui/themes/Mirage2/images/uji/logo_google.png)
![Microsoft Academico](/xmlui/themes/Mirage2/images/uji/logo_microsoft.png)
Metadata
Show full item recordcomunitat-uji-handle:10234/9
comunitat-uji-handle2:10234/7053
comunitat-uji-handle3:10234/8639
comunitat-uji-handle4:
INVESTIGACIONThis resource is restricted
http://dx.doi.org/10.1039/c6ra12731b |
Metadata
Title
Rational design of a supramolecular gel based on a Zn(II)–salophen bis-dipeptide derivativeAuthor (s)
Date
2016Publisher
Royal Society of ChemistryISSN
2046-2069Bibliographic citation
RSC Adv., 2016, 6, 57306Type
info:eu-repo/semantics/articleAbstract
We report the rational design and synthesis of a supramolecular gelator based on a Zn(II)–salophen derivative functionalized with L-valine residues. This compound is able to gelate acetonitrile by self-assembly into ... [+]
We report the rational design and synthesis of a supramolecular gelator based on a Zn(II)–salophen derivative functionalized with L-valine residues. This compound is able to gelate acetonitrile by self-assembly into helical long fibers that further aggregate into bundles. The fibers are stabilized by a network of hydrogen bonds and π–π stacking interactions established by gelator units stacked one on the top of another. The gel is responsive to the presence of anions. Moreover the zinc center remains available for the coordination of an external guest without causing gel disruption. [-]
Is part of
RSC Adv., 2016,6, 57306-57309Rights
This journal is © The Royal Society of Chemistry 2016
http://rightsstatements.org/vocab/InC/1.0/
info:eu-repo/semantics/restrictedAccess
http://rightsstatements.org/vocab/InC/1.0/
info:eu-repo/semantics/restrictedAccess
This item appears in the folowing collection(s)
- QUIO_Articles [701]