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Chemically Tunable Formation of Different Discrete, Oligomeric, and Polymeric Self‐Assembled Structures from Digold Metallotweezers
(2018)
Digold metallotweezers whose complex supramolecular landscape is controlled by adding a series of metal cations are described. The metallotweezers have a strong tendency to form interesting supramolecular structures on ...
Tuning optical/electrical properties of 2D/3D perovskite by the inclusion of aromatic cation
(Royal Society of Chemistry, 2018)
The employment of bulky aliphatic cations in the manufacture of moisture-stable materials has triggered
the development and application of 2D/3D perovskites as sensitizers in moisture-stable solar cells.
Although it is ...
Key factors in pincer ligand design
(Royal Society of Chemistry, 2018)
Pincers, tridentate ligands that prefer a meridional geometry, are a rising class because of their distinctive combination of properties. They permit a good level of control on the nature of the coordination sphere by ...
Paramagnetic ionic liquid-coated SiO2@Fe3O4 nanoparticles—The next generation of magnetically recoverable nanocatalysts applied in the glycolysis of PET
(Elsevier, 2020-01)
The functionalization of silica-coated, magnetic Fe3O4 nanoparticles, with an iron-containing ionic liquid, allows for the synthesis of a Fe3O4@SiO2@(mim)[FeCl4] system that can be employed as a magnetically recoverable ...
Ruthenium(II) pincer complexes featuring an anionicCNC bis(1,2,3-triazol-5-ylidene)carbazolide ligand coordinatedin a meridional fashion
(Elsevier, 2018)
The preparation of a new neutral ruthenium(II) pincer complexes with formula [RuCl(CO)2(CTRZNCTRZ)]
(CNC = bis(1,2,3-triazol-5-ylidene)carbazolide) is described. Access to the hydrido complex [RuH
(CO)2(CTRZNCTRZ)] was ...
Redox‐Active Hybrid Polyoxometalate‐Stabilised Gold Nanoparticles
(Wiley, 2020-08-17)
We report the design and preparation of multifunctional hybrid nanomaterials through the stabilization of gold nanoparticles with thiol‐functionalised hybrid organic–inorganic polyoxometalates (POMs). The covalent attachment ...
Improving Catalyst Activity in Hydrocarbon Functionalization by Remote Pyrene-Graphene Stacking
(Wiley, 2019)
A copper complex bearing an N-heterocyclic carbene ligand with a pyrene "tail" attached to the backbone has been prepared and supported on reduced graphene oxide (rGO). The free and supported copper materials have been ...
Perovskite Solar Cell Modeling Using Light- and Voltage-Modulated Techniques
(American Chemical Society, 2019-02-27)
The analysis of the impedance spectroscopy (IS) data of perovskite solar cells (PSCs) has been challenging so far, with the low-frequency phenomena in particular yielding ambivalent results and interpretations. We tackle ...
Effects of chain length on the size, stability, and electronic structure of redox-active organic– inorganic hybrid polyoxometalate micelles
(Royal Society of Chemistry, 2019)
Double-chain redox-active surfactants based on hybrid polyoxometalates show solvent-dependent assembly into nanoscale micellar architectures. These organic–inorganic hybrid amphiphiles, of the general formula K6[P2W17O61 ...
Morphology and Band Structure of Orthorhombic PbS Nanoplatelets: An Indirect Band Gap Material
(American Chemical Society, 2021-01-12)
PbS quantum dots and nanoplatelets (NPLs) are of enormous interest in the development of optoelectronic devices. However, some important aspects of their nature remain unclear. Recent studies have revealed that colloidal ...