Green bioprocesses in sponge-like ionic liquids
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Other documents of the author: Lozano, Pedro; Bernal, Juana M.; Gómez, Celia; Garcia-Verdugo, Eduardo; Burguete, M. Isabel; Sánchez Gómez, Gregorio; Vaultier, Michel; Luis, Santiago V.
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http://dx.doi.org/10.1016/j.cattod.2014.08.025 |
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Title
Green bioprocesses in sponge-like ionic liquidsAuthor (s)
Date
2015-10-15Publisher
ElsevierISSN
0920-5861Bibliographic citation
LOZANO, Pedro, et al. Green bioprocesses in sponge-like ionic liquids. Catalysis Today, 2015, vol. 255, p. 54-59Type
info:eu-repo/semantics/articlePublisher version
http://www.sciencedirect.com/science/article/pii/S0920586114006087Subject
Abstract
Ionic liquids (ILs) are a new class of liquid solvent, whose use has led to a green chemical revolution because of their unique array of physico-chemical properties, headed by their negligible vapour pressure and their ... [+]
Ionic liquids (ILs) are a new class of liquid solvent, whose use has led to a green chemical revolution because of their unique array of physico-chemical properties, headed by their negligible vapour pressure and their exceptional ability to stabilize biocatalysts. Hydrophobic ILs based on cations with long alkyl side-chains, e.g. N,N,N,N-hexadecyltrimethylammonium bis(trifluoromethylsulfonyl)imide ([C16tma][NTf2]), are temperature switchable ionic liquid/solid phases that behave as sponge-like systems (sponge-like ionic liquid, SLILs). Based on this new property, SLILs have been used to develop straightforward and clean approaches for producing nearly pure synthetic compounds with added value (e.g. geranyl acetate, anisyl acetate, methyl oleate, etc.) in two steps: an enzymatic synthetic step as liquid phase, and then a product separation step involving simple centrifugation as a solid phase. [-]
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Catalysis Today, 2015, vol. 255Rights
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