A nano-sized Janus di-N-heterocyclic carbene ligand based on a quinoxalinophenanthrophenazine core, and its coordina- tion to iridium
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Títol
A nano-sized Janus di-N-heterocyclic carbene ligand based on a quinoxalinophenanthrophenazine core, and its coordina- tion to iridiumData de publicació
2015-04-21Editor
American Chemical SocietyISSN
0276-7333Cita bibliogràfica
VALDÉS, Hugo; POYATOS, Macarena; PERIS, Eduardo. A Nanosized Janus Bis-N-heterocyclic Carbene Ligand Based on a Quinoxalinophenanthrophenazine Core, and Its Coordination to Iridium. Organometallics, 2015.Tipus de document
info:eu-repo/semantics/articleVersió de l'editorial
http://pubs.acs.org/doi/abs/10.1021/acs.organomet.5b00208Paraules clau / Matèries
Resum
A Janus-type bis-N-heterocyclic carbene ligand based on a quinoxalinophenanthrophenazine core has been obtained and coordinated to iridium. The electronic properties of the ligand have been determined on the basis of ... [+]
A Janus-type bis-N-heterocyclic carbene ligand based on a quinoxalinophenanthrophenazine core has been obtained and coordinated to iridium. The electronic properties of the ligand have been determined on the basis of an evaluation of the Tolman electronic parameter values. The new ligand disposes the two metals at a distance of 22.4 Å, significantly longer than in any of the related ligands reported so far. [-]
Publicat a
Organometallics, 2015, Vol. 34, n. 9Drets d'accés
Copyright © 2015 American Chemical Society
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info:eu-repo/semantics/openAccess
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info:eu-repo/semantics/openAccess
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