Listar QOMCAT_ Articles por título
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Post-Modification of the Electronic Properties by Addition of π-Stacking Additives in N-Heterocyclic Carbene Complexes with Extended Polyaromatic Systems
American Chemical Society (2015-03-17)A series of iridium complexes containing phenanthro[4,5-abc]phenazino[11,12-d]imidazol-2-ylidene and acetonaphtho[1,2-b]quinoxaline[11,12-d]imidazol-2-ylidene ligands have been obtained and fully characterized. These ... -
Ruthenium complexes with an N-heterocyclic carbene NNC-pincer ligand: preparation and catalytic properties
Royal Society of Chemistry (2015-06)1-Methyl-3-(2-((pyridin-2-ylmethylene)amino)ethyl)-1H-imidazol-3-ium bromide was prepared and used as an N-heterocyclic carbene NNC-pincer ligand precursor. Depending on the coordination strategy, a monometallic ... -
Unveiling the Importance of π-Stacking in Borrowing-Hydrogen Processes Catalysed by Iridium Complexes with Pyrene Tags
Wiley (2015-09-10)This work describes the preparation of a series of pyrene-tagged N-heterocyclic carbene complexes of iridium, and their use in two benchmark borrowing hydrogen reactions: the reduction of ketones by transfer hydrogenation ...