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A pyrene-based N‑heterocyclic carbene: study of its coordination chemistry and stereoelectronic properties
dc.contributor.author | Valdés Rivas, Hugo Christian | |
dc.contributor.author | Poyatos, Macarena | |
dc.contributor.author | Peris, Eduardo | |
dc.date.accessioned | 2015-06-17T19:03:47Z | |
dc.date.available | 2015-06-17T19:03:47Z | |
dc.date.issued | 2014 | |
dc.identifier.issn | 0276-7333 | |
dc.identifier.issn | 1520-6041 | |
dc.identifier.uri | http://hdl.handle.net/10234/123813 | |
dc.description.abstract | A new pyrene-N-heterocyclic carbene ligand has been obtained and coordinated to rhodium and iridium, affording the corresponding [MCl(NHC)(COD)] and [MCl(NHC)(CO)2] complexes (M = Ir, Rh). The presence of the pyrene backbone allows the introduction of a η6 -bonded [RuCp]+ fragment and facilitates the formation of the corresponding heterometallic complexes of Rh/Ru and Ir/Ru. The stereoelectronic properties of the new ligand have been studied by means of IR spectroscopy and cyclic voltammetry and demonstrate that the introduction of the [RuCp]+ fragment results in the reduction of the electron-donating power of the ligand | ca_CA |
dc.format.extent | 8 p. | ca_CA |
dc.language.iso | eng | ca_CA |
dc.publisher | American Chemical Society | ca_CA |
dc.relation.isPartOf | Organometallics 2014, 33, 394−401 | ca_CA |
dc.rights | © 2013 American Chemical Society | ca_CA |
dc.rights.uri | http://rightsstatements.org/vocab/InC/1.0/ | * |
dc.title | A pyrene-based N‑heterocyclic carbene: study of its coordination chemistry and stereoelectronic properties | ca_CA |
dc.type | info:eu-repo/semantics/article | ca_CA |
dc.identifier.doi | http://dx.doi.org/dx.doi.org/10.1021/om401134w | |
dc.rights.accessRights | info:eu-repo/semantics/restrictedAccess | ca_CA |
dc.relation.publisherVersion | http://bs8lz6ys5q.search.serialssolutions.com/?ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info:sid/summon.serialssolutions.com&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=A+Pyrene-Based+N-Heterocyclic+Carbene%3A+Study+of+Its+Coordination+Chemistry+and+Stereoelectronic+Properties&rft.jtitle=ORGANOMETALLICS&rft.au=Valdes%2C+H&rft.au=Poyatos%2C+M&rft.au=Peris%2C+E&rft.date=2014-01-13&rft.pub=AMER+CHEMICAL+SOC&rft.issn=0276-7333&rft.eissn=1520-6041&rft.volume=33&rft.issue=1&rft.spage=394&rft.epage=401&rft_id=info:doi/10.1021%2Fom401134w&rft.externalDBID=n%2Fa&rft.externalDocID=000329879900046¶mdict=ca | ca_CA |
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