In situ synthesis-gelation at room temperature vs. heating–cooling procedure. Fine tuning of molecular gels derived from succinic acid and L-valine
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http://dx.doi.org/10.1016/j.jcis.2013.08.055 |
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Títol
In situ synthesis-gelation at room temperature vs. heating–cooling procedure. Fine tuning of molecular gels derived from succinic acid and L-valineData de publicació
2013-12Editor
ElsevierCita bibliogràfica
FONTANILLO, Miriam, et al. In situ synthesis-gelation at room temperature vs. heating–cooling procedure. Fine tuning of molecular gels derived from succinic acid and L-valine. Journal of colloid and interface science, 2013, 412: 65-71.Tipus de document
info:eu-repo/semantics/articleVersió de l'editorial
http://www.sciencedirect.com/science/article/pii/S0021979713008217Paraules clau / Matèries
Resum
Hypothesis
The reaction between succinic anhydride and a diamine derived from L-valine should afford efficiently a molecular gelator. Based on this reaction, it should be feasible to prepare molecular gels at room ... [+]
Hypothesis
The reaction between succinic anhydride and a diamine derived from L-valine should afford efficiently a molecular gelator. Based on this reaction, it should be feasible to prepare molecular gels at room temperature, avoiding the conventional thermal treatment required for the solubilization of the gelator, by in situ, simultaneous, synthesis and gelation. The gels prepared by in situ and conventional heating–cooling protocols could present important differences relevant for potential practical applications of these materials.
Experimental
The gelator was synthesized by reaction of succinic anhydride and a diamine derived from L-valine, affording two new amide bonds. The molecular gels were studied by IR, NMR, electron microscopy, X-ray diffraction and DSC.
Findings
The results indicate that different polymorphic fibrillar networks are formed depending on the gel preparation method, highlighting how the properties of molecular gels can be tuned in this way. Significant differences between thermal and in situ gels were found in properties such as thermal stability, thixotropic behavior or release of an entrapped dye. In situ synthesis-gelation has also been shown to provide gels in media such as oleic acid which cannot be jellified by conventional heating–cooling procedures. [-]
Publicat a
Journal of Colloid and Interface Science Volume 412, 15 December 2013Drets d'accés
Copyright © 2014 Elsevier B.V.
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info:eu-repo/semantics/restrictedAccess
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