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Pyracene-Linked Bis-Imidazolylidene Complexes of Palladium and Some Catalytic Benefits Produced by Bimetallic Catalysts
dc.contributor.author | Guisado-Barrios, Gregorio | |
dc.contributor.author | Hiller, Joanna | |
dc.contributor.author | Peris, Eduardo | |
dc.date.accessioned | 2014-05-13T10:28:36Z | |
dc.date.available | 2014-05-13T10:28:36Z | |
dc.date.issued | 2013-06-18 | |
dc.identifier.citation | GUISADO‐BARRIOS, Gregorio; HILLER, Joanna; PERIS, Eduardo. Pyracene‐Linked Bis‐Imidazolylidene Complexes of Palladium and Some Catalytic Benefits Produced by Bimetallic Catalysts. Chemistry-A European Journal, 2013, vol. 19, no 31, p. 10405-10411 | ca_CA |
dc.identifier.issn | 0947-6539 | |
dc.identifier.issn | 1521-3765 | |
dc.identifier.uri | http://hdl.handle.net/10234/92126 | |
dc.description.abstract | Two new palladium complexes with a pyracene-linked bis-imidazolylidene (pyrabim) group have been obtained and fully characterized. The related monometallic analogues were obtained from the coordination of an acetanaphthene-supported N-heterocyclic carbene (NHC). The catalytic properties of all complexes were studied in the acylation of aryl halides with hydrocinnamaldehyde, and in the Suzuki–Miyaura coupling of aryl halides and aryl boronic acids. The results show that the presence of a second metal in the dimetallic complexes induces some benefits in the catalytic behavior of the complexes. This effect is more pronounced in the Suzuki–Miyaura coupling, for which the dimetallic complexes exhibit significantly higher activity than their monometallic counterparts. | ca_CA |
dc.format.extent | 7 p. | ca_CA |
dc.format.mimetype | application/pdf | ca_CA |
dc.language.iso | eng | ca_CA |
dc.publisher | Wiley | ca_CA |
dc.relation.isPartOf | Chemistry-A European Journal, 2013, vol. 19, no 31 | ca_CA |
dc.rights | Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim | ca_CA |
dc.rights.uri | http://rightsstatements.org/vocab/InC/1.0/ | * |
dc.subject | acylation | ca_CA |
dc.subject | carbenes | ca_CA |
dc.subject | C-C coupling | ca_CA |
dc.subject | homogeneous catalysis | ca_CA |
dc.subject | palladium | ca_CA |
dc.title | Pyracene-Linked Bis-Imidazolylidene Complexes of Palladium and Some Catalytic Benefits Produced by Bimetallic Catalysts | ca_CA |
dc.type | info:eu-repo/semantics/article | ca_CA |
dc.identifier.doi | http://dx.doi.org/10.1002/chem.201300486 | |
dc.rights.accessRights | info:eu-repo/semantics/restrictedAccess | ca_CA |
dc.relation.publisherVersion | http://onlinelibrary.wiley.com/doi/10.1002/chem.201300486/full | ca_CA |
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