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Chemoenzymatic synthesis of optically active 2-(2- or 4-substituted-1H-imidazol-1-yl)cycloalcanols. Chiral additives for (L)-proline
dc.contributor.author | Porcar Garcia, Raul | |
dc.contributor.author | Ríos-Lombardía, Nicolás | |
dc.contributor.author | Busto, Eduardo | |
dc.contributor.author | Gotor Fernández, Vicente | |
dc.contributor.author | Gotor Fernández, Vicente | |
dc.contributor.author | Garcia-Verdugo, Eduardo | |
dc.contributor.author | Burguete, M. Isabel | |
dc.contributor.author | Luis, Santiago V. | |
dc.date.accessioned | 2014-05-09T07:24:58Z | |
dc.date.available | 2014-05-09T07:24:58Z | |
dc.date.issued | 2013-04-03 | |
dc.identifier.citation | PORCAR, Raul, et al. Chemoenzymatic synthesis of optically active 2-(2′-or 4′-substituted-1 H-imidazol-1-yl) cycloalkanols: chiral additives for (l)-proline. Catalysis Science & Technology, 2013, vol. 3, no 10, p. 2596-2601 | ca_CA |
dc.identifier.issn | 2044-4753 | |
dc.identifier.uri | http://hdl.handle.net/10234/91791 | |
dc.description.abstract | Enantiopure substituted imidazoles obtained by enzymatic kinetic resolution can be promising candidates as co-catalysts for aldol reactions catalysed by (L)-proline. These additives seem to form supramolecular complexes with the catalyst through the formation of H-bonds, leading to significant improvement in both the reaction rates and selectivity of the reaction. Herein, we present our results on the use of these substituted trans-2-imidazoyl-cycloalkanols as additives for the (L)-proline catalyzed direct aldol reaction between ketones and aromatic aldehydes. | ca_CA |
dc.format.extent | 6 p. | ca_CA |
dc.format.mimetype | application/pdf | ca_CA |
dc.language.iso | eng | ca_CA |
dc.publisher | Royal Society of Chemistry | ca_CA |
dc.relation.isPartOf | Catalysis Science & Technology, 2013, vol. 3, no 10 | ca_CA |
dc.rights | © Royal Society of Chemistry 2014 | ca_CA |
dc.rights.uri | http://rightsstatements.org/vocab/InC/1.0/ | * |
dc.subject | Direct aldol reaction | ca_CA |
dc.subject | Asymmetric organocatalysis | ca_CA |
dc.subject | Aromatic aldehyde | ca_CA |
dc.subject | Chemo-enzymatic synthesis | ca_CA |
dc.subject | Chiral additives | ca_CA |
dc.subject | Enzymatic kinetic resolutions | ca_CA |
dc.subject | Optically Active | ca_CA |
dc.subject | Supramolecular complexes | ca_CA |
dc.title | Chemoenzymatic synthesis of optically active 2-(2- or 4-substituted-1H-imidazol-1-yl)cycloalcanols. Chiral additives for (L)-proline | ca_CA |
dc.type | info:eu-repo/semantics/article | ca_CA |
dc.identifier.doi | http://dx.doi.org/10.1039/C3CY00107E | |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | ca_CA |
dc.relation.publisherVersion | http://pubs.rsc.org/en/Content/ArticleLanding/2013/CY/c3cy00107e#!divAbstract | ca_CA |
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