Listar UJI: Investigación por autoría "72bc3d6e-df54-4f6b-aeca-444d878e15e6"
Mostrando ítems 1-4 de 4
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Introducing Ion Mobility Mass Spectrometry to Identify Site-Selective C–H Bond Activation in N-Heterocyclic Carbene Metal Complexes
Mollar Cuni, Andrés; Ibañez-Ibañez, Laura; Guisado-Barrios, Gregorio; Mata Martínez, Jose A; Vicent Barrera, Cristian American Chemical Society (2022-11-14)The activation of C−H bonds in a selective manner still constitutes a major challenge from a synthetic point of view; thus, it remains an active area of fundamental and applied research. Herein, we introduce ion mobility ... -
Ion mobility mass spectrometry uncovers regioselectivity in the carboxylate-assisted C–H activation of palladium N-heterocyclic carbene complexes
Ibañez-Ibañez, Laura; Mollar Cuni, Andrés; Apaloo-Messan , Edmond; Sharma, Akhilesh Kumar; Mata Martínez, Jose A; Maseras, Feliu; Vicent Barrera, Cristian Royal Society of Chemistry (2023-11-27)Carboxylate-assisted Pd-catalyzed C–H bond activation constitutes a mild and versatile synthetic tool to efficiently and selectively cleave inert C–H bonds. Herein, we demonstrate a simple method to experimentally evaluate ... -
Visible light harvesting alkyne hydrosilylation mediated by pincer platinum complexe
Ibañez-Ibañez, Laura; Lázaro, Ariadna; Mejuto, Carmen; Crespo, Margarita; Vicent Barrera, Cristian; Rodríguez, Laura; Mata Martínez, Jose A Elsevier (2023-12)In this manuscript we assess the catalytic properties of pincer platinum complexes in alkyne hydrosilylation either under photo or thermal conditions. The visible light-induced hydrosilylation proved to be more efficient. ... -
Visible-Light-Promoted Iridium(III)-Catalyzed Acceptorless Dehydrogenation of N-Heterocycles at Room Temperature
Mejuto, Carmen; Ibañez-Ibañez, Laura; Guisado-Barrios, Gregorio; Mata Martínez, Jose A American Chemical Society (2022-05-10)An effective visible-light-promoted iridium(III)-catalyzed hydrogen production from N-heterocycles is described. A single iridium complex constitutes the photocatalytic system playing a dual task, harvesting visible-light ...