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New {RuNO} Polyoxometalate [PW11O39RuII(NO)]4-: Synthesis and Reactivity
dc.contributor.author | Sokolov, Maxim | |
dc.contributor.author | Adonin, Sergey A. | |
dc.contributor.author | Mainichev, Dmitry A. | |
dc.contributor.author | Sinkevich, Pavel L. | |
dc.contributor.author | Vicent Barrera, Cristian | |
dc.contributor.author | Kompankov, Nikolay B. | |
dc.contributor.author | Gushchin, Artem L. | |
dc.contributor.author | Nadolinny, V. A. | |
dc.contributor.author | Fedin, Vladimir P. | |
dc.date.accessioned | 2014-04-08T14:50:48Z | |
dc.date.available | 2014-04-08T14:50:48Z | |
dc.date.issued | 2013 | |
dc.identifier.citation | Inorg. Chem., 2013, 52 (16), pp 9675–9682 | ca_CA |
dc.identifier.issn | 0020-1669 | |
dc.identifier.issn | 1520-510X | |
dc.identifier.uri | http://hdl.handle.net/10234/89810 | |
dc.description.abstract | New Ru-containing polyoxometalate [PW11O39RuII(NO)]4- (14-) was obtained in high yield by reaction of [Ru(NO)Cl5]2- with [PW11O39]7- and characterized by multinuclear NMR, cyclic voltammetry, IR spectroscopy, and electrospray ionization mass spectrometry (ESI-MS). The intrinsic reactivity of the {RuNO} site in 14- toward various reagents has been studied using a versatile and simple ESI tandem mass spectrometric methodology for identification of the L attached at the Ru site; this approach relies on the preferential liberation of the L ligands attached at the Ru sites upon mass-selecting desired intermediates and subsequent promotion of their fragmentation. Reactions with both hydrazine and hydroxylamine lead to elimination of the nitroso group and quantitative formation of [PW11O39RuIII(H2O)]4- (24-) in aqueous solution. In the reaction with hydroxylamine, an intermediate with coordinated dinitrogen has been detected. An easy access to the NH3-coordinated [PW11O39RuNH3]4- (34-) complex was achieved upon reduction of 14- with Sn2+ in water. | ca_CA |
dc.format.extent | 7 p. | ca_CA |
dc.format.mimetype | application/pdf | ca_CA |
dc.language.iso | eng | ca_CA |
dc.publisher | American Chemical Society | ca_CA |
dc.relation.isPartOf | Inorganic Chemistry, 2013, vol. 52, no 16 | ca_CA |
dc.rights | Copyright © 2013 American Chemical Society | ca_CA |
dc.rights.uri | http://rightsstatements.org/vocab/InC/1.0/ | * |
dc.subject | New {RuNO} Polyoxometalate [PW11O39RuII(NO)]4- | ca_CA |
dc.title | New {RuNO} Polyoxometalate [PW11O39RuII(NO)]4-: Synthesis and Reactivity | ca_CA |
dc.type | info:eu-repo/semantics/article | ca_CA |
dc.identifier.doi | http://dx.doi.org/10.1021/ic401492q | |
dc.rights.accessRights | info:eu-repo/semantics/restrictedAccess | ca_CA |
dc.relation.publisherVersion | http://pubs.acs.org/doi/abs/10.1021/ic401492q | ca_CA |
dc.type.version | info:eu-repo/semantics/publishedVersion | ca_CA |
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