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dc.contributor.authorSokolov, Maxim
dc.contributor.authorAdonin, Sergey A.
dc.contributor.authorMainichev, Dmitry A.
dc.contributor.authorSinkevich, Pavel L.
dc.contributor.authorVicent Barrera, Cristian
dc.contributor.authorKompankov, Nikolay B.
dc.contributor.authorGushchin, Artem L.
dc.contributor.authorNadolinny, V. A.
dc.contributor.authorFedin, Vladimir P.
dc.date.accessioned2014-04-08T14:50:48Z
dc.date.available2014-04-08T14:50:48Z
dc.date.issued2013
dc.identifier.citationInorg. Chem., 2013, 52 (16), pp 9675–9682ca_CA
dc.identifier.issn0020-1669
dc.identifier.issn1520-510X
dc.identifier.urihttp://hdl.handle.net/10234/89810
dc.description.abstractNew Ru-containing polyoxometalate [PW11O39RuII(NO)]4- (14-) was obtained in high yield by reaction of [Ru(NO)Cl5]2- with [PW11O39]7- and characterized by multinuclear NMR, cyclic voltammetry, IR spectroscopy, and electrospray ionization mass spectrometry (ESI-MS). The intrinsic reactivity of the {RuNO} site in 14- toward various reagents has been studied using a versatile and simple ESI tandem mass spectrometric methodology for identification of the L attached at the Ru site; this approach relies on the preferential liberation of the L ligands attached at the Ru sites upon mass-selecting desired intermediates and subsequent promotion of their fragmentation. Reactions with both hydrazine and hydroxylamine lead to elimination of the nitroso group and quantitative formation of [PW11O39RuIII(H2O)]4- (24-) in aqueous solution. In the reaction with hydroxylamine, an intermediate with coordinated dinitrogen has been detected. An easy access to the NH3-coordinated [PW11O39RuNH3]4- (34-) complex was achieved upon reduction of 14- with Sn2+ in water.ca_CA
dc.format.extent7 p.ca_CA
dc.format.mimetypeapplication/pdfca_CA
dc.language.isoengca_CA
dc.publisherAmerican Chemical Societyca_CA
dc.relation.isPartOfInorganic Chemistry, 2013, vol. 52, no 16ca_CA
dc.rightsCopyright © 2013 American Chemical Societyca_CA
dc.rights.urihttp://rightsstatements.org/vocab/InC/1.0/*
dc.subjectNew {RuNO} Polyoxometalate [PW11O39RuII(NO)]4-ca_CA
dc.titleNew {RuNO} Polyoxometalate [PW11O39RuII(NO)]4-: Synthesis and Reactivityca_CA
dc.typeinfo:eu-repo/semantics/articleca_CA
dc.identifier.doihttp://dx.doi.org/10.1021/ic401492q
dc.rights.accessRightsinfo:eu-repo/semantics/restrictedAccessca_CA
dc.relation.publisherVersionhttp://pubs.acs.org/doi/abs/10.1021/ic401492qca_CA
dc.type.versioninfo:eu-repo/semantics/publishedVersionca_CA


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