Browsing QUIO_Articles by Source "Dalton Transactions. 2013, 42"
Now showing items 1-2 of 2
-
Dithiolene dimetallic molybdenum(V) complexes displaying intraligand charge transfer (ILCT) emission
Royal Society of Chemistry (2013)Bifunctional dithiolene ligands have been coordinated to the MoV(O)(μ-S2)MoV(O) unit to afford [Mo2O2(μ-S)2(BPyDTS2)2]2− (12−) (BPyDTS2 (2-bis-(2-pyridyl)methylene-1,3-dithiolene) dianions. Reaction of the 12− molybdenum ... -
Rhodium–NHC complexes mediate diboration versus dehydrogenative borylation of cyclic olefins: a theoretical explanation†
Royal Society of Chemistry (2013)In rhodium catalysed borylation of cyclic olefins, the synergy between bidentate NHC ligands, that modify cationic Rh(I) species, and the use of non-polar solvents, such as cyclohexane, is the key factor to favour a less ...