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A resorcinarene-based tetrabenzoimidazolylidene complex of rhodium
Royal Society of Chemistry (2020-03-14)A tetrabenzoimidazolium-resorcinarene cavitand was used for the preparation of a tetra-benzoimidazolylidene of rhodium, which is unprecedented in the field of poly-NHC metal complexes. Both, the experimental and computational ... -
A review of recent advances of kesterite thin films based on magnesium, iron and nickel for photovoltaic application: insights into synthesis, characterization and optoelectronic properties
Oxford University Press (2024-03-26)This review emphasizes the recent advancements and prospects of thin-film kesterite-based photovoltaic (PV) applications using magnesium, iron and nickel. The quest for novel materials employed in solar cells has resulted ... -
A rhodium(I)–oxygen adduct as a selective catalyst for one-pot sequential alkyne dimerization-hydrothiolation tandem reactions
Royal Society of Chemistry (2016-01)An air-stable rhodium(I)–oxygen adduct featuring a CNC-pincer ligand, based on 1,2,3-triazol-5-ylidenes, catalyzes the homo-dimerization and hydrothiolation of alkynes, affording the gem-enyne and α-vinyl sulfide isomers, ... -
A simple peptidomimetic that self-associates on the solid state to form a nanoporous architecture containing chiral π-channels
Royal Society of Chemistry (2010)The crystal structure of a simple peptidomimetic compound, derived from phenylalanine, shows the formation of a nanoporous architecture containing monodimensional p-channels with the aromatic rings as the exclusive ... -
A Simple Route to Chelating, Structurally Different Triazole-Based Bis(N-heterocyclic carbene) Ligands and Their Coordination to PtIl
Wiley (2011-01)Two new bis(triazolium) salts have been prepared and used as N-heterocyclic carbene (NHC) precursors. The structure of the salts is highly dependent on the synthetic route, which implies the sequential alkylation of two ... -
A simple, safe and robust system for hydrogenation "without high-pressure gases" under batch and flow conditions using a liquid organic hydrogen carrier
Royal Society of Chemistry (2022)A simple, safe and robust system for the continuous, in situ and on demand generation of hydrogen under mild conditions is reported. A device formed by a packed bed reactor containing a ruthenium N-heterocyclic carbene ... -
A site-selective fluorescence spectroscopy study of the crystal phases of KY3F10: Leveraging the optical response of Eu3+ ions
Elsevier (2023-04-18)The present work deals with the investigation of the site-selective symmetries in Eu3+-doped KY3F10 with different crystal phases. Employing time-resolved fluorescence line-narrowing (TRFLN), a study of the luminescent ... -
A spectroscopic study to assess the photogeneration of singlet oxygen by graphene oxide
Elsevier (2019)The photogeneration of singlet oxygen (1 O2) during short irradiation times of graphene oxide (GO) is assessed under visible light with soft irradiation conditions either directly monitoring the phosphorescence emission ... -
A Study of the Interaction between a Family of Gemini Amphiphilic Pseudopeptides and Model Monomolecular Film Membranes Formed with a Cardiolipin
American Chemical Society (2015-05)The interaction between five gemini amphiphilic pseudopeptides (GAPs) differing by the length of the central spacer and a model membrane lipid, 1,3-bis[1,2-dimyristoyl-sn-glycero-3-phospho]-sn-glycerol (cardiolipin) were ... -
A Tetracyclic Bis(imidazolindiylidene) Ligand and Its Diiridium and Dipalladium Complexes
American Chemical Society (2013)A bis(imidazolidine) with two butylene linkers between the nitrogen atoms of the adjacent heterocycles has been prepared. This tetracyclic molecule can be coordinated to iridium and palladium following two different ... -
A voltammetric electronic tongue for the quantitative analysis of quality parameters in wastewater
Wiley (2017-01-18)The use of a voltammetric electronic tongue for the quantitative analysis of quality parameters in influent wastewater from a wastewater treatment plant (WWTP) that treats domestic and industrial wastewater is proposed. ... -
A Y-Shaped tris-N-heterocyclic carbene for the synthesis of simultaneously chelate-monodentate dipalladium complexes
American Chemical Society (2011-11)A Y-shaped tris-NHC ligand has been obtained and coordinated to palladium, affording metal complexes with novel topological properties. The tris-NHC ligand is capable of coordinating the two metals, affording two different ... -
Active biopolymers in green non-conventional media: a sustainable tool for developing clean chemical processes
Royal Society of Chemistry (2015-10-15)The greenness of chemical processes turns around two main axes: the selectivity of catalytic transformations, and the separation of pure products. The transfer of the exquisite catalytic efficiency shown by enzymes in ... -
Acyclic Pseudopeptidic Hosts as Molecular Receptors and Transporters for Anions
Wiley-VCH Verlag (2015)The synthesis and characterization of different pseudopeptidic hosts derived from open chain systems with C2 and C3 symmetry has been achieved. These receptors are based on structures containing phenylalanine amino acid ... -
Adsorption of Rose Bengal on a self-assembled fibrillar network affords a thermally switchable oxygenation photocatalyst and a thermochromic soft material
Elsevier (2019-10-03)Rose Bengal (RB) can be homogeneously dispersed in dichloromethane by its adsorption on the fibrillar network of a molecular gel formed in this solvent. The RB loaded gel was visualized by confocal scanning laser microscopy, ... -
Advances in the Development of SARS-CoV-2 Mpro Inhibitors
MDPI (2022-04-14)Since the outbreak of COVID-19, one of the strategies used to search for new drugs has been to find inhibitors of the main protease (Mpro) of the virus SARS-CoV-2. Initially, previously reported inhibitors of related ... -
Ag Nanoparticles/α-Ag2WO4 Composite Formed by Electron Beam and Femtosecond Irradiation as Potent Antifungal and Antitumor Agents
Nature Research (2019)The ability to manipulate the structure and function of promising systems via external stimuli is emerging with the development of reconfigurable and programmable multifunctional materials. Increasing antifungal and antitumor ... -
Aldol Reactions between L-Erythrulose Derivatives and Chiral α-Amino and α -Fluoro Aldehydes: Competition between Felkin–Anh and Cornforth Transition States
Wiley-Blackwell (2008)Both matched and mismatched diastereoselection have been observed in aldol reactions of a boron enolate of a protected l-erythrulose derivative with several chiral α-fluoro and α-Amino aldehydes. Strict adherence to the ... -
Alkaline cations dramatically control molecular hydrogelation by an amino acid-derived anionic amphiphile
Elsevier (2023-01-03)Understanding the factors that control the formation of (supra)molecular hydrogels permits a rational tuning of their properties and represents a primary challenge for developing smart biocompatible soft materials. Hydrogel ... -
Alkenyl-functionalized NHC iridium-based catalysts for hydrosilylation
Royal Society of Chemistry (2008)A family of alkenyl-functionalized N-heterocyclic-carbene–iridium(I) complexes has been synthesized, providing a series of mono-coordinated, bis-chelate and pincer alkenyl-NHC species. Olefin coordination is highly ...