Listar QUIO_Articles por autoría "e3e9973a-86a0-45d9-8c92-8ec991c334a0"
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Intramolecular oxidation of the alcohol functionalities in hydroxyalkyl-n-heterocyclic carbene complexes of iridium and rhodium
Benítez Gómez, Miriam; Mas, Elena; Mata Martínez, Jose A; Peris, Eduardo WILEY-VCH Verlag (2011-08-04)A series of hydroxyalkyl-functionalized imidazolium salts have been coordinated to Rh and Ir to afford the corresponding MCp*–(NHC) (Cp*=pentamethylcyclopentadienyl) complexes. The reactivity of the new complexes has been ... -
Rhodium and Iridium Complexes with Chelating C–C′-Imidazolylidene–Pyridylidene Ligands: Systematic Approach to Normal, Abnormal, and Remote Coordination Modes
Segarra, Candela; Mas, Elena; Mata Martínez, Jose A; Peris, Eduardo American Chemical Society (2012)A series of linked imidazolium−pyridinium salts ([Him-pyH](X)2 ) have been used as imidazolylidene− pyridylidene ligand precursors for the preparation of rhodium- (III) and iridium(III) complexes. The relative configuration ... -
Shvo’s catalyst and [IrCp*Cl2(amidine)] effectively catalyze the formation of tertiary amines from the reaction of primary alcohols and ammonium salts
Segarra, Candela; Mas, Elena; Mata Martínez, Jose A; Peris, Eduardo Wiley (2011-08-04)The reaction of (pentamethylcyclopentadienyl)iridium dichloride dimer, [IrCp*Cl2]2, with bis(2,4,6-trimethylphenyl)formamidine allows the preparation of two new [IrCp*Cl2(amidine)] and [IrCp*Cl(amidinate)] complexes, which ... -
Synthesis and Properties of Chelating N-Heterocyclic Carbene Rhodium(I) Complexes: Synthetic Experiments in Current Organometallic Chemistry.
Mas, Elena; Mata Martínez, Jose A; Poyatos, Macarena © 2011 The American Chemical Society and Division of Chemical Education (2011-03)The preparation and characterization of two air-stable Rh(I) complexes bearing a chelating N-heterocyclic carbene (NHC) ligand is described. The synthesis involves the preparation of a Ag(I)-NHC complex and its use as ... -
Water Oxidation at Hematite Photoelectrodes with an Iridium-Based Catalyst
Badia Bou, Laura; Mas, Elena; Rodenas, Pau; Barea, Eva M; Fabregat-Santiago, Francisco; Gimenez, Sixto; Peris, Eduardo; Bisquert, Juan American Chemical Society (2013)The iridium complex [Cp*Ir(H2O)3](SO 4) was used as an organometallic source for the electrodeposition of iridium oxide onto Fe2O3. The new iridium-containing electrode allowed us to study the coupling between the ...