Visualitza QUIO_Articles per autoria "c6859e5b-ed14-4576-92a6-a1a3c675cf1e"
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Divergent Multistep Continuous Synthetic Transformations of Allylic Alcohol Enabled by Catalysts Immobilized in Ionic Liquid Phases
Peris, Edgar; Porcar Garcia, Raul; García-Álvarez, Joaquín; Burguete, M. Isabel; Garcia-Verdugo, Eduardo; Luis, Santiago V. Wiley (2019-04-23)Two individual catalytic platforms (metal‐ and organo‐catalyzed) based on the use of an ionic liquid phase were successfully integrated for the synthesis of α‐cyano‐amine and cyanohydrin trimethylsilyl ethers from allylic ... -
Supported ionic liquid-like phases as organocatalysts for the solvent-free cyanosilylation of carbonyl compounds: from batch to continuous flow process
Martín, Sergio; Porcar Garcia, Raul; Peris, Edgar; Burguete, M. Isabel; Garcia-Verdugo, Eduardo; Luis, Santiago V. Royal Society of Chemistry (2014)Supported ionic liquid-like phases (SILLPs) are able to efficiently catalyse the cyanosilylation of carbonyl compounds using trimethylsilyl cyanide under solvent-free conditions. These organic catalysts were efficient for ... -
Supported Ionic Liquid‐Like Phases (SILLPs) as Immobilised Catalysts for the Multistep and Multicatalytic Continuous Flow Synthesis of Chiral Cyanohydrins
Peris, Edgar; Porcar Garcia, Raul; Burguete, M. Isabel; Garcia-Verdugo, Eduardo; Luis, Santiago V. (2019)Supported Ionic Liquid‐Like Phases have been found to be efficient organocatalysts for the synthesis of cyanohydrin esters under solvent‐free conditions by an “electrophile‐nucleophile dual activation” based on hydrogen ... -
Synergy between supported ionic liquid-like phases and immobilized palladium N-heterocyclic carbene–phosphine complexes for the Negishi reaction under flow conditions
Peris, Edgar; Porcar Garcia, Raul; Maciá, María; Alcázar, Jesús; Garcia-Verdugo, Eduardo; Luis, Santiago V. Beilstein-Institut (2020)The combination of supported ionic liquids and immobilized NHC–Pd–RuPhos led to active and more stable systems for the Negishi reaction under continuous flow conditions than those solely based on NHC–Pd–RuPhos. The fine ... -
Tuneable 3D printed bioreactors for transaminations under continuous-flow
Peris, Edgar; Okafor, Obinna; Kulcinskaja, Evelina; Goodridge, Ruth; Luis, Santiago V.; Garcia-Verdugo, Eduardo; O'Reilly, Elaine; Sans, Victor Royal Society of Chemistry (2017-11-21)A method to efficiently immobilize enzymes on 3D printed continuous- fl ow devices is presented. Application of these chemically modi fi ed devices enables rapid screening of immobilization mechanisms and ...