Visualitza QFA_Articles per paraule clau "tungsten"
Ara mostrant els elements 1-3 d 3
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The Role of Solvent on the Mechanism of Proton Transfer to Hydride Complexes: The Case of the [W3PdS4H3(dmpe)3(CO)]+ Cubane Cluster
Wiley-VCH (2010)The kinetics of reaction of the [W3PdS4H3(dmpe)3(CO)]+ hydride cluster (1+) with HCl has been measured in dichloromethane, and a second-order dependence with respect to the acid is found for the initial step. In the presence ... -
Tri- and tetranuclear chalcogenide molybdenum and tungsten clusters: on the way to new materials and catalysts
Turpion (2018)The information about electronic structure, redox, magnetic, luminescent, non-linear and catalytic properties of tri- and tetranuclear chalcogenide molybdenum and tungsten clusters is summarized. Prospects of their ... -
Unprecedented Solvent-Assisted Reactivity of Hydrido W3CuS4 Cubane Clusters: The Non-Innocent Behaviour of the Cluster-Core Unit
Wiley (2009)Opening the cluster core: Substitution of the chloride ligand in the novel cationic cluster [W3CuS4H3Cl(dmpe)3]+ (see figure; dmpe=1,2-bis(dimethylphosphino)ethane) by acetonitrile is promoted by water addition. Kinetic ...