Listar QFA_Articles por autoría "c6da215d-0c7a-48c9-8655-12262fe19d60"
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Chemoselective Hydrogenation of Nitroarenes Catalyzed by Molybdenum Sulphide Clusters
Pedrajas Gual, Elena; Sorribes, Iván; Gushchin, Artem L.; Laricheva, Yuliya A.; Junge, Henrik; Beller, matthias; Llusar, Rosa Wiley (2017-03-20)Herein, we describe an atom efficient and general protocol for the chemoselective hydrogenation of nitroarenes to anilines catalyzed by well-defined diimino and diamino cubane-type Mo3S4 clusters. The novel diimino ... -
Cycloaddition of alkynes to diimino Mo3S4 cubane-type clusters: a combined experimental and theoretical approach
Pino Chamorro, Jose Angel; Laricheva, Yuliya A.; Guillamón, Eva; Fernández-Trujillo, M. Jesús; Bustelo, Emilio; Gushchin, Artem L.; Shmelev, Nikita Y.; Abramov, Pavel A.; Sokolov, Maxim; Llusar, Rosa; García Basallote, Manuel; Algarra, Andrés G. Royal Society of Chemistry (2016)A heterocyclic ligand 4,4′-di-tert-butyl-2,2′-bipyridine (dbbpy) has been coordinated to the Mo3S4 cluster unit affording the complex [Mo3S4Cl3(dbbpy)3]+ ([1]+) in a one-step ligand-exchange protocol from [Mo3S4(tu)8(H2O)]Cl4·4H2O ... -
Homoleptic Molybdenum Cluster Sulfides Functionalized with Noninnocent Diimine Ligands: Synthesis, Structure, and Redox Behavior
Gushchin, Artem L.; Laricheva, Yuliya A.; Abramov, Pavel A.; Virovets, Alexander V.; Vicent Barrera, Cristian; Sokolov, Maxim; Llusar, Rosa Wiley (2014)Thiourea (tu) has been coordinated to the Mo3S44+ cluster unit to afford the new cluster compound [Mo3S4(tu)8(H2O)]Cl4·4H2O (1). The high substitutional lability of the thiourea ligands can be exploited to achieve smooth ... -
Kinetics Aspects of the Reversible Assembly of Copper in Heterometallic Mo3CuS4 Clusters with 4,4′-Di-tert-butyl-2,2′-bipyridine
Pino Chamorro, Jose Angel; Laricheva, Yuliya A.; Guillamón, Eva; Fernández-Trujillo, M. Jesús; Algarra, Andrés G.; Gushchin, Artem L.; Abramov, Pavel A.; Bustelo, Emilio; Llusar, Rosa; Sokolov, Maxim; García Basallote, Manuel American Chemical Society (2016)Treatment of the triangular [Mo3S4Cl3(dbbpy)3]Cl cluster ([1]Cl) with CuCl produces a novel tetrametallic cuboidal cluster [Mo3(CuCl)S4Cl3(dbbpy)3][CuCl2] ([2][CuCl2]), whose crystal structure was determined by X-ray ... -
Photogeneration of Hydrogen from Water by Hybrid Molybdenum Sulfide Clusters Immobilized on Titania
Recatalá Ferrandis, David; Llusar, Rosa; Gushchin, Artem L.; Kozlova, Ekaterina A.; Laricheva, Yuliya A.; Abramov, Pavel A.; Sokolov, Maxim; Gómez, Roberto; Lana-Villarreal, Teresa John Wiley & Sons (2015)Two new hybrid molybdenum(IV) Mo3S7 cluster complexes derivatized with diimino ligands have been prepared by replacement of the two bromine atoms of [Mo3S7Br6]2− by a substituted bipyridine ligand to afford heteroleptic ... -
Tri- and tetranuclear chalcogenide molybdenum and tungsten clusters: on the way to new materials and catalysts
Gushchin, Artem L.; Laricheva, Yuliya A.; Sokolov, Maxim; Llusar, Rosa Turpion (2018)The information about electronic structure, redox, magnetic, luminescent, non-linear and catalytic properties of tri- and tetranuclear chalcogenide molybdenum and tungsten clusters is summarized. Prospects of their ...