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Ara mostrant els elements 1-2 d 2
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Selective synthesis of triangular cluster oxido-sulfidocomplexes of Mo and W: High yield preparations of [Mo3O2S2(H2O)9]4+, [W3O2S2(H2O)9]4+, [W2MoO2S2(H2O)9]4+ and their derivatization
Abramov, Pavel A.; Sokolov, Maxim; Hernández Molina, Rita; Vicent Barrera, Cristian; Virovets, Alexander V.; Naumov, Dmitry Yu; Gili, Pedro; González Platas, Javier; Fedin, Vladimir P. Elsevier (2010)Reaction of [Mo2O2(μ-S)2(H2O)6]2+ with Mo(CO)6 or metallic Mo under hydrothermal conditions (140 °C, 4 M HCl) gives oxido-sulfido cluster aqua complex [Mo3(μ3-S)(μ-O)2(μ-S)(H2O)9]4+ (1). Similarly, [W3(μ3-S)(μ-O)2(μ-S)(H2O)9]4+ ... -
Theoretical calculations on aseries of dinuclear vanadium and niobium clusters
Safont Villarreal, Vicent Sixte; Hernández Molina, Rita; Gili, Pedro; Sokolov, Maxim Elsevier (2011)Electronic structures of chalcogenide-bridged binuclear clusters of vanadium and niobium with the {M2(μ-Q2)2}4+, {M2(μ-Q)2}4+ and {M2(μ-Q)(μ-Q)2}4+ cores (Q = S, Se, Te) have been studied by density functional theory ...