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Triazolyl-based molecular gels as ligands for autocatalytic ‘click’reactions
(Wiley, 2016)
The catalytic performance of triazolyl-based molecular gels was investigated in the Huisgen 1,3-dipolar cycloaddition of alkynes and azides. Low-molecular-weight gelators derived from l-valine were synthesized and ...
Direct anodic hydrochloric acid and cathodic caustic production during water electrolysis
(Nature Publishing Group, 2016)
Hydrochloric acid (HCl) and caustic (NaOH) are among the most widely used chemicals by the water
industry. Direct anodic electrochemical HCl production by water electrolysis has not been successful
as current commercially ...
Design, synthesis and antimalarial evaluation of novel thiazole derivatives
(Elsevier, 2016)
As part of our medicinal chemistry program’s ongoing search for compounds with antimalarial activity, we prepared a series of thiazole analogs and conducted a SAR study analyzing their in vitro activities against the ...
Ferromagnetic Ligand Holes in Cobalt Perovskite Electrocatalysts as Essential Factor for High Activity Towards Oxygen Evolution
(Royal Society of Chemistry, 2019)
The definition of the interplay between chemical composition, electro-magnetic configuration and
catalytic activity requires a rational study of the orbital physics behind active materials. Apart from
Coulomb forces, ...
Quantum Mechanics/Molecular Mechanics Studies of the Mechanism of Cysteine Proteases Inhibition by Dipeptidyl Nitroalkenes
(Wiley, 2020-02-11)
In this work a computational study of the mechanism of inhibition of cruzain, rhodesain, and cathepsin L cysteine proteases by the dipeptidyl nitroalkene Cbz‐Phe‐Ala‐CH=CH‐NO2 has been carried out by means of molecular ...
Nucleophilic T-Shaped (LXL)Au(I)-Pincer Complexes: Protonation and Alkylation
(American Chemical Society, 2016-11)
We report the synthesis and reactivity of unusual T-shaped (LXL)Au(I)-pincer complexes, based on a carbazole framework flanked by two mesoionic carbenes (MICs). In contrast to other Au(I) complexes, these complexes react ...
Catalytic Hydrogen Production by Ruthenium Complexes from the Conversion of Primary Amines to Nitriles: Potential Application as a Liquid Organic Hydrogen Carrier
(Wiley, 2016)
The potential application of the primary amine/nitrile pair as a liquid organic hydrogen carrier (LOHC) has been evaluated. Ruthenium complexes of formula [(p-cym)Ru(NHC)Cl2] (NHC=N-heterocyclic carbene) catalyze the ...
Characterization of amine stabilized CdSe/ZnS core–shell quantum dots by using triarylpyrylium dyes
(Royal Society of Chemistry, 2016-06-13)
A new method to study the stabilizing primary amine ligands coordinated to the surface of CdSe/ZnS core–shell quantum dots has been developed. The method is based on the reactivity of fluorescent 2,4,6-triarylpyrylium dyes ...
Pseudopeptidic fluorescent on-off pH sensor based on pyrene excimer emission: Imaging of acidic cellular organelles
(Elsevier, 2016)
A pseudopeptidic compound comprising a central C2 symmetric bis(aminoamide) moiety derived from the amino acid serine and two pyrene groups at the ends, Et(SerPyr)2, has been efficiently prepared. In aqueous solution, it ...
Time resolved fluorescence of naproxen in organogel medium
(Elsevier, 2008)
The interaction between non-steroidal anti-inflammatory drug naproxen and the self assembled fibrillar network created by a low molecular weight organogelator has been probed by means of time resolved fluorescence spectroscopy.