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AuNP−polymeric ionic liquid composite multicatalytic nanoreactors for one-pot cascade reactions
(American Chemical Society, 2016)
Different AuNP-PIL nanocomposites have been developed
as bifunctional catalysts in which the IL-like units promote the Knoevenagel
condensation through a dual electrophilic/nucleophilic activation relay
mechanism and ...
Stereoselective recognition of the Ac-Glu-Tyr-OH dipeptide by pseudopeptidic cages
(Royal Society of Chemistry, 2015)
Pseudopeptidic molecular cages are appealing receptors since they can display different polar and nonpolar
interaction sites in a modular framework and a controlled disposition. Inspired by previous host–
guest knowledge, ...
Tight and Selective Caging of Chloride Ions by a Pseudopeptidic Host
(WILEY-VCH Verlag GmbH & Co. KGaA, 2014-06)
The selective molecular recognition of chloride versus similar anions is a continuous challenge in supramolecular chemistry. We have designed and prepared a simple pseudopeptidic cage (1 a) that defines a cavity suitable ...
Pseudopeptidic Cages as Receptors for N-Protected Dipeptides
(American Chemical Society, 2014-04)
The molecular recognition of short peptides is a challenge in supramolecular chemistry, and the use of peptide-like cage receptors represents a promising approach. Here we report the synthesis and characterization of a ...
Bis(amino amides) derived from natural amino acids as chiral receptors for N-protected dicarboxylic amino acids
(Elsevier, 2013-01)
A family of bis(amino amides) derived from natural amino acids has been synthesized and tested for the NMR enantiodiscrimination, as chiral receptors, of some N-protected dicarboxylic amino acids. The influence of the amino ...
Ion Mobility Mass Spectrometry Uncovers Guest-Induced Distortions in a Supramolecular Organometallic Metallosquare
(Wiley, 2021)
The encapsulation of the tetracationic palladiummetallosquare with four pyrene-bis-imidazolylidene ligands[1]4+with aseries of organic molecules was studied byElectrosprayionization Travelling Wave Ion-Mobility MassSpectrometry ...
Cp*Ir(NHC) complexes as highly versatile and efficient catalysts for the cross-coupling of alcohols and amines
(Wiley-VCH, 2008-11-19)
A comparative study on the catalytic activity of a series of Cp*Ir(NHC)Cl2
complexes in several C-O and C-N coupling processes implying hydrogen-borrowing
mechanisms has been performed. The compound Cp*Ir(InBu)Cl2 (InBu ...
Upgrading biomass to high-added value chemicals: synthesis of monoterpenes-based compounds using catalytic green chemical pathways
(Elsevier, 2024-04-08)
Monoterpenes derived from various biomass constitute an important platform for synthesizing fragrances, intermediates, and pharmaceuticals. In this review, the most recent and relevant transformations of terpenes are ...
Bis (imidazolium) salts derived from amino acids as receptors and transport agents for chloride anions
(Royal Society of Chemistry, 2015-04)
The binding properties of bis(imidazolium) hosts 1a–c derived from amino acids towards different anions have been studied by 1H NMR titration experiments in 95[thin space (1/6-em)]:[thin space (1/6-em)]05 CD3CN[thin space ...
Stereoselective synthesis of the naturally occurring 2-pyranone dodoneine
(Wiley-VCH, 2008-08)
The first total synthesis of the naturally occurring dihydropyranone dodoneine is reported. Asymmetric allylations were
used for the stereoselective generation of the two stereogenic centers. The pyranone ring was created ...