ListarDepartament: Química Inorgànica i Orgànica por tema "mesoionic carbene"
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A Hemilabile and Cooperative N-Donor-Functionalized 1,2,3-Triazol-5-Ylidene Ligand for Alkyne Hydrothiolation Reactions
Wiley (2017)A series of novel cationic and neutral Rh complexes with an N-donor-functionalized 1,2,3-triazol-5-ylidene (TRZ) ligand (in which the pendant N donor is NHBoc, NH2, or NMe2) is described. The catalytic activity of these ... -
Triazolium Salts as Appropriate Catalytic Scaffolds for 1,4-Additions toα,β-Unsaturated Carbonyls
Wiley Online Library (2014)1,2,3-Triazole derivatives containing a rigid dihydroanthracenyl skeleton are suitable precursors for both organometallic and organo-based catalysts. A Rh–carbene complex and the triazolium salt efficiently catalyzed the ...