Browsing Departament: Química Inorgànica i Orgànica by Keyword "Aldol reaction"
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Double diastereoselection in anti aldol reactions mediated by dicyclohexylchloroborane between an L-erythrulose derivative and chiral aldehydes
Royal Society of Chemistry (2012)Anti aldol reactions of an L-erythrulose derivative with several α-chiral aldehydes mediated by dicyclohexylboron chloride are examined. Good yields and stereoselectivities are observed. The results are best explained ... -
Substrate selective catalytic molecular hydrogels: the role of the hydrophobic effect
Royal Society of Chemistry (2013-09-17)A catalytic hydrogel is reported for the substrate selective direct aldol reaction of aliphatic ketones based on their hydrophobicity and on the emergence of catalytic activity only after self-assembly of the catalyst. -
Supramolecular Interactions Based on Ionic Liquids for Tuning of the Catalytic Efficiency of (L)-Proline
American Chemical Society (2016-09)Noncovalent intermolecular interactions between (l)-proline and ionic liquids (ILs) are key to explain the different catalytic efficiencies observed for this organocatalyst in the aldol reaction carried out in ILs or in ...