Browsing Departament: Química Inorgànica i Orgànica by Keyword "Aldehydes"
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Dual setereocontrolled alkylation of aldehydes with polystyrene-supported nickel complexes derived from a-amino amides
Royal Society of Chemistry (2015-01)Nickel(II) complexes derived from α-amino amide ligands anchored to gel-type and monolithic polymers act as efficient catalysts for the enantioselective addition of dialkylzinc reagents to aldehydes. Similar to the analogous ... -
Short, Stereoselective Synthesis of the Naturally Occurring Pyrrolidine Radicamine B and a Formal Synthesis of Nectrisine
American Chemical Society (2008)A short, stereoselective synthesis of the naturally occurring pyrrolidine radicamine B is reported. Garner′s (R)-aldehyde, prepared from d-serine, was the chiral starting material. The pyrrolidine ring was stereoselectively ...