Browsing Departament: Química Inorgànica i Orgànica by Keyword "α-amino amides"
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Mechanistic implications of the enantioselective addition of alkylzinc reagents to aldehydes catalyzed by nickel complexes with a-amino amide ligands
The Royal Society of Chemistry (2016-11)The enantioselective alkylation of aldehydes catalysed by nickel(II)-complexes derived from α-amino amides was studied by means of density functional theory (DFT) and ONIOM (B3LYP:UFF) calculations. A mechanism was proposed ...