Listar Departament: Química Inorgànica i Orgànica por autoría "197dc9ce-e27b-4077-9b6e-939c140661ce"
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Heterometallic complexes, tandem catalysis and catalytic cooperativity
Mata Martínez, Jose A; Hahn, Franz Ekkehardt; Peris, Eduardo The Royal Society of Chemistry (2014)This minireview reports the most recent advances in the use of heterometallic catalysts based on single-frame N-heterocyclic carbene ligands. The article describes the synthetic strategies for the preparation of heterometallic ... -
Hexanuclear cylinder-shaped assemblies of silver and gold from benzene−hexa-N-heterocyclic carbenes
Segarra, Candela; Guisado-Barrios, Gregorio; Hahn, Franz Ekkehardt; Peris, Eduardo American Chemical Society (2014)In this work we describe the preparation of a new benzene–hexaimidazolylidene ligand, which we have coordinated to silver and gold. The new complexes constitute unique examples of cylinder-like macromolecular arrangements, ... -
Synthesis and Characterization of Poly-NHC-Derived Silver(I) Assemblies and Their Transformation into Poly-Imidazolium Macrocycles
Gutiérrez-Blanco, Ana; Dobbe, Christian B.; Hepp, Alexander; Daniliuc, Constantin G.; Poyatos, Macarena; Hahn, Franz Ekkehardt; Peris, Eduardo Wiley-VCH GmbH (2021-04-22)Three metallosupramolecular assemblies composed of two bis-NHCs and two silver atoms, [4](PF6)2, two tetra-NHCs and foursilver atoms, [7](PF6)4, and two tri-NHCs and three silver atoms[8](BF4)3, have been prepared. Assemblies ... -
Synthesis of nanometer-sized cylinder-like structures from a 1,3,5- triphenylbenzene-bridged tris-NHC ligand and AgI , AuI , and CuI
Sinha, Narayan; Roelfes, Florian; Hepp, Alexander; Mejuto, Carmen; Peris, Eduardo; Hahn, Franz Ekkehardt American Chemical Society (2014)The metal-controlled self-assembly of nanometer-sized trinuclear cylinder-like assemblies is described. The 1,3,5-triphenylbenzene-derived trisimidazolium salt [1](PF6)3 reacts with 1.5 equiv of Ag2O to yield the ...