Listar Departament: Química Inorgànica i Orgànica por autoría "0bfbed19-42cc-4f5a-a735-38cdbf1a76b6"
Mostrando ítems 1-7 de 7
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Ferrocenyl-Imidazolylidene Ligand for Redox-Switchable Gold-Based Catalysis. A Detailed Study on the Redox-Switching Abilities of the Ligand
Ibáñez, Susana; Poyatos, Macarena; Dawe, Louise N.; Gusev, Dmitry; Peris, Eduardo American Chemical Society (2016)An imidazolium salt with a fused benzoferrocenyl was synthesized. This compound was used as an N-heterocyclic carbene (NHC) precursor, and the related ferrocenyl-imidazolylidene complexes Fc-NHC-MLn (MLn = IrCl(COD), ... -
First homoleptic MIC and heteroleptic NHC-MIC coordination cages from 1,3,5-triphenylbenzene-bridged tris-MIC and tris-NHC ligands
Mejuto, Carmen; Guisado-Barrios, Gregorio; Gusev, Dmitry; Peris, Eduardo Royal Society of Chemistry (2015-07-24)The preparation of a triphenylbenzene-bridged tris-(1,2,3-triazolium) salt allowed us to obtain the first homoleptic tris-MIC cylinder-like cages of Ag and Au. The silver MIC-based cage reacts with the trisNHC-Ag analogue ... -
Imidazolidines as hydride sources for the formation of late transition-metal monohydrides
Poyatos, Macarena; Prades Ferrer, Amparo; Gonell, Sergio; Gusev, Dmitry; Peris, Eduardo Royal Society of Chemistry (2012)The reaction of a series of imidazolidines with chloro-complexes of Ir, Rh and Ru affords the clean generation of the corresponding monohydrido metal species. Computational analysis of the reduction process suggests that ... -
Ion Mobility Mass Spectrometry Uncovers Guest-Induced Distortions in a Supramolecular Organometallic Metallosquare
Vicent Barrera, Cristian; Martínez Agramunt, Víctor; Gandhi, Viraj; Larriba, Carlos; Gusev, Dmitry; Peris, Eduardo Wiley (2021)The encapsulation of the tetracationic palladiummetallosquare with four pyrene-bis-imidazolylidene ligands[1]4+with aseries of organic molecules was studied byElectrosprayionization Travelling Wave Ion-Mobility MassSpectrometry ... -
Ruthenium complexes with an N-heterocyclic carbene NNC-pincer ligand: preparation and catalytic properties
Mejuto, Carmen; García-Eleno, Marco A.; Guisado-Barrios, Gregorio; Spasyuk, Denis; Gusev, Dmitry; Peris, Eduardo Royal Society of Chemistry (2015-06)1-Methyl-3-(2-((pyridin-2-ylmethylene)amino)ethyl)-1H-imidazol-3-ium bromide was prepared and used as an N-heterocyclic carbene NNC-pincer ligand precursor. Depending on the coordination strategy, a monometallic ... -
The Tolman electronic parameter (TEP) and the metal–metal electronic communication in ditopic NHC complexes
Gusev, Dmitry; Peris, Eduardo Royal Society of Chemistry (2013)Whereas the electronic communication between metals in dimetallic organometallic compounds is often assessed through cyclic voltammetric measurements, we have found that the variations in the Tolman electronic parameter ... -
Tuning the Catalytic Activity of a Pincer Complex of Rhodium(I) by Supramolecular and Redox Stimuli
Martínez-Vivas, Sebastián; Gusev, Dmitry; Poyatos, Macarena; Peris, Eduardo Wiley (2023)We report the rhodium(I) complex [Rh(CNC−NDI)(CO)]+, in which CNC−NDI refers to a pincer-CNC ligand decorated with a naphthalenediimide moiety. Due to the presence of the planar CNC ligand and the naphthalenediimide moiety, ...