Browsing Departament: Química Física i Analítica by Keyword "palladium"
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Palladium doping of In2O3 towards a general and selective catalytic hydrogenation of amides to amines and alcohols
Royal Society of Chemistry (2019-11)Herein, the first general heterogeneous catalytic protocol for the hydrogenation of primary, secondary and tertiary amides to their corresponding amines and alcohols is described. Advantageously, this catalytic protocol ... -
The Role of Solvent on the Mechanism of Proton Transfer to Hydride Complexes: The Case of the [W3PdS4H3(dmpe)3(CO)]+ Cubane Cluster
Wiley-VCH (2010)The kinetics of reaction of the [W3PdS4H3(dmpe)3(CO)]+ hydride cluster (1+) with HCl has been measured in dichloromethane, and a second-order dependence with respect to the acid is found for the initial step. In the presence ...