Synthesis of chiral room temperature ionic liquids from amino acids – application in chiral molecular recognition
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http://dx.doi.org/10.1002/ejoc.201200607 |
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Títol
Synthesis of chiral room temperature ionic liquids from amino acids – application in chiral molecular recognitionAutoria
Data de publicació
2012Editor
Wiley-VCH VerlagISSN
1434-193X; 1099-0690Tipus de document
info:eu-repo/semantics/articleVersió de l'editorial
http://onlinelibrary.wiley.com/doi/10.1002/ejoc.201200607/pdfhttp://www.interscience.wiley.com
Paraules clau / Matèries
Resum
A series of structurally new room temperature chiral ionic
liquids based on an imidazolium group and derived from natural amino acids have been synthesized and studied as chiral
shift agents for the chiral discrim ... [+]
A series of structurally new room temperature chiral ionic
liquids based on an imidazolium group and derived from natural amino acids have been synthesized and studied as chiral
shift agents for the chiral discrimination of enantiomeric
carboxylate salts. This family of imidazolium salts can be prepared by a simple synthetic approach and most of the components are liquid at room temperature. The solid to liquid
transformation temperatures can be as low as –49 °C. The
analysis of the supramolecular structure of the resulting CILs
can be used advantageously to understand the potential for
the selective recognition of different hosts. [-]
Publicat a
Eur. J. Org. Chem. 2012Drets d'accés
© Wiley-VCH Verlag
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