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Dual Catalysis with an IrIII–AuI Heterodimetallic Complex: Reduction of Nitroarenes by Transfer Hydrogenation using Primary Alcohols
dc.contributor.author | Sabater López, Sara | |
dc.contributor.author | Peris, Eduardo | |
dc.contributor.author | Mata Martínez, Jose A | |
dc.date.accessioned | 2013-05-30T09:14:13Z | |
dc.date.available | 2013-05-30T09:14:13Z | |
dc.date.issued | 2012-05 | |
dc.identifier.issn | 0947-6539 | |
dc.identifier.uri | http://hdl.handle.net/10234/65194 | |
dc.description.abstract | A triazolyl-di-ylidene ligand has been used for the preparation of a homodimetallic complex of gold, and a heterodimetallic compound of gold and iridium. Both complexes have been fully characterized and their molecular structures have been determined by means of X-ray diffraction. The catalytic properties of these two complexes have been evaluated in the reduction of nitroarenes by transfer hydrogenation using primary alcohols. The two complexes afford different reaction products; whereas the AuI–AuI catalyst yields a hydroxylamine, the IrIII–AuI complex facilitates the formation of an imine. | ca_CA |
dc.format.extent | 6 p. | ca_CA |
dc.format.mimetype | application/pdf | ca_CA |
dc.language.iso | eng | ca_CA |
dc.publisher | Wiley | ca_CA |
dc.relation.isPartOf | Chemistry - A European Journal, 2012, Vol. 18, num. 20 | ca_CA |
dc.rights | Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim | ca_CA |
dc.rights.uri | http://rightsstatements.org/vocab/InC/1.0/ | * |
dc.subject | Gold | ca_CA |
dc.subject | Heterometallic complexes | ca_CA |
dc.subject | Hydrogenation | ca_CA |
dc.subject | Iridium | ca_CA |
dc.subject | Oxidation | ca_CA |
dc.subject | Reduction | ca_CA |
dc.title | Dual Catalysis with an IrIII–AuI Heterodimetallic Complex: Reduction of Nitroarenes by Transfer Hydrogenation using Primary Alcohols | ca_CA |
dc.type | info:eu-repo/semantics/article | ca_CA |
dc.identifier.doi | http://dx.doi.org/10.1002/chem.201103657 | |
dc.rights.accessRights | info:eu-repo/semantics/restrictedAccess | ca_CA |
dc.relation.publisherVersion | http://onlinelibrary.wiley.com/doi/10.1002/chem.201103657/full | ca_CA |
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