Synthesis and Properties of Chelating N-Heterocyclic Carbene Rhodium(I) Complexes: Synthetic Experiments in Current Organometallic Chemistry.
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comunitat-uji-handle2:10234/7053
comunitat-uji-handle3:10234/8639
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http://dx.doi.org/10.1021/ed100952d |
Metadatos
Título
Synthesis and Properties of Chelating N-Heterocyclic Carbene Rhodium(I) Complexes: Synthetic Experiments in Current Organometallic Chemistry.Fecha de publicación
2011-03Editor
© 2011 The American Chemical Society and Division of Chemical EducationISSN
0021-9584Tipo de documento
info:eu-repo/semantics/articleVersión de la editorial
http://pubs.acs.org/doi/abs/10.1021/ed100952dPalabras clave / Materias
Resumen
The preparation and characterization of two air-stable Rh(I) complexes bearing a chelating N-heterocyclic carbene (NHC) ligand is described. The synthesis involves the preparation of a Ag(I)-NHC complex and its use ... [+]
The preparation and characterization of two air-stable Rh(I) complexes bearing a chelating N-heterocyclic carbene (NHC) ligand is described. The synthesis involves the preparation of a Ag(I)-NHC complex and its use as carbene transfer agent to a Rh(I) precursor. The so obtained complex can be further reacted with carbon monoxide to give the corresponding carbonyl derivative. The students will be able to identify the products using standard characterization techniques such as NMR and IR spectroscopy. The required equipment is typically available in most of the standard laboratories for undergraduate students. (Contains 2 figures and 3 schemes.) [-]
Publicado en
Journal of Chemical Education (March 2011), vol. 88, no. 6, 822–824Derechos de acceso
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info:eu-repo/semantics/restrictedAccess
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